去除沼气中的CO2和H2S,提高猪粪和象草压缩生物甲烷气体的产量

N. Dussadee, Kamoldara Reansuwan, Rameshprabu Ramaraj, Yuwalee Unpaprom
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摘要

采用浓缩猪粪与象草青贮的厌氧共消化工艺,在中温条件下,在3个连续搅拌槽式反应器中进行了研究。采用分子筛和活性炭对沼气除杂过程进行了强化。两个分子筛罐用于从沼气中吸收水分。在进入储气罐之前,使用一个2米的活性炭罐将H2S滤除至< 1ppm。压缩生物甲烷气(CBG)产量为1.44万m3/d (CH4 60-70%), CBG产量为9600 m3/d(6.8吨/d)。当H2S浓度为768 ppm时,沼气CH4、CO2和O2的含量分别为68.8%、29.7%和0%。在< 0.01 ppm H2S条件下,CBG的CH4、CO2、O2含量分别为89.35%、10.05%和0.02%。因此,经过净化处理后,CO2、H2S气体的体积量大大减少,CH4的体积量提高了90%,然后将CBG压缩到250 bar的罐中作为汽车燃料。因此,这些结果清楚地表明,活性炭法在大型工厂中去除沼气中的CO2和H2S是可行的。
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Removal of CO2 and H2S from biogas and enhanced compressed bio-methane gas production from swine manure and elephant grass
Anaerobic co-digestion of concentrated swine manure with elephant grass silage was used, and this study carried out in full-scale three continuously stirred tank reactors was operated at mesophilic temperature. The Biogas impurity removal procedure was enhanced by using a molecular sieve and activated carbon. Two molecular sieve tanks are used to absorb water from the biogas. An activated carbon tank (2 meters) was used to eliminate H2S to < 1 ppm before entering the gas tank. In the form of compressed bio-methane gas (CBG), production was 14,400 m3/day (CH4 60-70%), and the amount of CBG was 9,600 m3/day 6.8 tons/day. The raw biogas containing CH4, CO2, and O2 are 68.8%, 29.7% and 0% with H2S 768 ppm. After the enhancement process, CBG having CH4, CO2, O2 are 89.35%, 10.05 0% and 0.02% with < 0.01 ppm H2S. Therefore, after the purification process amount of CO2, H2S gas was considerably reduced and CH4 was improved by up to 90% by volume, and then the CBG was compressed to 250 bar tanks to the fuel for cars. Therefore, these results clearly demonstrate that the activated carbon method is feasible to process for the removal of CO2 and H2S from biogas in a large-scale plant.
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