Miscible blends of a vinylidene chloride/vinyl chloride copolymer with polymethacrylates

A copolymer of vinylidene chloride and vinyl chloride containing 13.5% of the latter has been found to form completely miscible blends with atactic and isotactic poly(methyl methacrylate). poly(ethyl methacrylate), poly(n-propyl methacrylate), and poly(cyclohexyl methacrylate). All but the latter of these blends were shown to exhibit lower critical solution temperature behavior at temperatures below that at which the copolymer rapidly degrades. The copolymer was found to be only partially miscible with poly(isopropyl methacrylate), while no detectable level of miscibility was observed with poly(methyl acrylate), poly(ethyl acrylate), poly(vinyl acetate), poly(vinyl methyl ether), or poly(vinyl methyl ketone). Information about interactions between components in the miscible blends was estimated from melting point data and is discussed.