青蒿水提物介导的纳米钯生物合成及其对铃木偶联反应的催化评价

F. Ahmadi, M. Hekmati, M. Yousefi, H. Veisi
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引用次数: 8

摘要

研究了一种简单的生物制备钯纳米粒子(Pd NPs)的方法,该方法采用无毒、可持续的天然青蒿提取物作为还原、稳定和封盖剂。利用紫外可见光谱(UV-vis)、x射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、场发射扫描电镜(FE-SEM)、透射电镜(TEM)和能量色散x射线能谱(EDS)对合成的Pd NPs@Artemisia催化剂进行了分类。Pd NPs@Artemisia在Suzuki-Miyaura交叉偶联反应中表现出优异的可重复使用的纳米催化剂性能。该纳米催化剂可循环使用7次,催化活性无明显下降。
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Biogenic synthesis of Palladium nanoparticles mediated by Artemisia abrotanum aqueous extract and its catalytic evaluation for Suzuki coupling reactions
A simple and biological method for the fabrication of palladium nanoparticles (Pd NPs) was developed, applying the non-toxic and sustainable natural extract from Artemisia abrotanum as the reducing, stabilizing and capping agent. UV-vis spectroscopy, X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS), were utilized to classify the synthesized Pd NPs@Artemisia catalyst. The Pd NPs@Artemisia demonstrated excellent behavior as a reusable nanocatalyst in Suzuki-Miyaura cross-coupling reactions at room temperature. The nanocatalyst was recycled 7 times without any significant deduction in catalytic activity.
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