赤铁矿的光电化学

Y. Maeda
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引用次数: 0

摘要

将氧化铁电化学沉积在水溶液中,并在500℃以上的空气中进行热处理,可以制备赤铁矿薄膜。介绍了电流脉冲法和电位脉冲法沉积氧化铁膜的过程,并讨论了氧化铁的平衡电位。赤铁矿水溶液在可见光照射下表现出明显的光阳极电流。以柠檬酸、铅和苯胺为例,综述了赤铁矿电极对水溶液中有机和无机物的光氧化反应。
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Photoelectrochemistry of Hematite
It was possible to prepare a hematite film by electrochemical deposition of iron oxide in aqueous solution and its heat treatment at 500 C or higher temperature in air. The deposition process of iron oxide film from current and potential pulse methods was mentioned in relation to the equilibrium potential for iron oxide. The hematite in aqueous solution showed a clear photoanodic current due to visible light irradiation. The photo-oxidation response of hematite electrode to organic and inorganic materials in aqueous solution was summarized through the examples of citric acid, Pb and aniline.
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