{"title":"从越南稻草废料中提取半纤维素、纤维素和羧甲基纤维素的研究","authors":"Mai Thi Tuyet Phan, Trang Thu La, T. H. A. Ngo","doi":"10.31276/VJSTE.63(1).15-20","DOIUrl":null,"url":null,"abstract":"extraction and CMC production. Abstract: Cellulose and hemicellulose were successfully extracted from Vietnamese rice straw waste. The maximum hemicellulose yield of the process was 22.60% with 1.5 M NaOH at 90 o C for 1.5 h. The pure cellulose obtained from the rice straw was prepared by refluxing the rice straw powder with a 1.0 M HNO 3 solution at 90 o C for 1.5 h. The Vietnamese rice straw cellulose was converted to carboxymethyl cellulose (CMC) by etherification. The extracted cellulose was soaked in a mixed solution of isopropyl alcohol and NaOH solution for 1.5 h. After that, it was reacted with monochloroacetic acid at 70 o C for 1.5 h. The optimum conditions for carboxymethylation were 5 g cellulose, 4.0 g monochloroacetic acid, and 15 ml 25% w/v NaOH and the obtained product had a degree of substitution (DS) of 0.70.","PeriodicalId":23548,"journal":{"name":"Vietnam Journal of Science, Technology and Engineering","volume":"16 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Study on extracting hemicellulose, cellulose, and carboxymethyl cellulose from Vietnamese rice straw waste\",\"authors\":\"Mai Thi Tuyet Phan, Trang Thu La, T. H. A. Ngo\",\"doi\":\"10.31276/VJSTE.63(1).15-20\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"extraction and CMC production. Abstract: Cellulose and hemicellulose were successfully extracted from Vietnamese rice straw waste. The maximum hemicellulose yield of the process was 22.60% with 1.5 M NaOH at 90 o C for 1.5 h. The pure cellulose obtained from the rice straw was prepared by refluxing the rice straw powder with a 1.0 M HNO 3 solution at 90 o C for 1.5 h. The Vietnamese rice straw cellulose was converted to carboxymethyl cellulose (CMC) by etherification. The extracted cellulose was soaked in a mixed solution of isopropyl alcohol and NaOH solution for 1.5 h. After that, it was reacted with monochloroacetic acid at 70 o C for 1.5 h. The optimum conditions for carboxymethylation were 5 g cellulose, 4.0 g monochloroacetic acid, and 15 ml 25% w/v NaOH and the obtained product had a degree of substitution (DS) of 0.70.\",\"PeriodicalId\":23548,\"journal\":{\"name\":\"Vietnam Journal of Science, Technology and Engineering\",\"volume\":\"16 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-03-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Vietnam Journal of Science, Technology and Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.31276/VJSTE.63(1).15-20\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vietnam Journal of Science, Technology and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.31276/VJSTE.63(1).15-20","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
摘要
提取和CMC生产。摘要/ Abstract摘要:从越南秸秆废料中成功提取纤维素和半纤维素。在1.5 M NaOH, 90℃,1.5 h条件下,半纤维素得率最高可达22.60%。将稻草粉与1.0 M hno3溶液,90℃,回流1.5 h,制得纯纤维素,通过醚化反应将越南稻草纤维素转化为羧甲基纤维素(CMC)。提取的纤维素在异丙醇和NaOH溶液的混合溶液中浸泡1.5 h,然后与一氯乙酸在70℃下反应1.5 h,羧甲基化的最佳条件为纤维素5 g,一氯乙酸4.0 g, NaOH 15 ml 25% w/v,所得产物的取代度(DS)为0.70。
Study on extracting hemicellulose, cellulose, and carboxymethyl cellulose from Vietnamese rice straw waste
extraction and CMC production. Abstract: Cellulose and hemicellulose were successfully extracted from Vietnamese rice straw waste. The maximum hemicellulose yield of the process was 22.60% with 1.5 M NaOH at 90 o C for 1.5 h. The pure cellulose obtained from the rice straw was prepared by refluxing the rice straw powder with a 1.0 M HNO 3 solution at 90 o C for 1.5 h. The Vietnamese rice straw cellulose was converted to carboxymethyl cellulose (CMC) by etherification. The extracted cellulose was soaked in a mixed solution of isopropyl alcohol and NaOH solution for 1.5 h. After that, it was reacted with monochloroacetic acid at 70 o C for 1.5 h. The optimum conditions for carboxymethylation were 5 g cellulose, 4.0 g monochloroacetic acid, and 15 ml 25% w/v NaOH and the obtained product had a degree of substitution (DS) of 0.70.