从越南稻草废料中提取半纤维素、纤维素和羧甲基纤维素的研究

Mai Thi Tuyet Phan, Trang Thu La, T. H. A. Ngo
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引用次数: 2

摘要

提取和CMC生产。摘要/ Abstract摘要:从越南秸秆废料中成功提取纤维素和半纤维素。在1.5 M NaOH, 90℃,1.5 h条件下,半纤维素得率最高可达22.60%。将稻草粉与1.0 M hno3溶液,90℃,回流1.5 h,制得纯纤维素,通过醚化反应将越南稻草纤维素转化为羧甲基纤维素(CMC)。提取的纤维素在异丙醇和NaOH溶液的混合溶液中浸泡1.5 h,然后与一氯乙酸在70℃下反应1.5 h,羧甲基化的最佳条件为纤维素5 g,一氯乙酸4.0 g, NaOH 15 ml 25% w/v,所得产物的取代度(DS)为0.70。
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Study on extracting hemicellulose, cellulose, and carboxymethyl cellulose from Vietnamese rice straw waste
extraction and CMC production. Abstract: Cellulose and hemicellulose were successfully extracted from Vietnamese rice straw waste. The maximum hemicellulose yield of the process was 22.60% with 1.5 M NaOH at 90 o C for 1.5 h. The pure cellulose obtained from the rice straw was prepared by refluxing the rice straw powder with a 1.0 M HNO 3 solution at 90 o C for 1.5 h. The Vietnamese rice straw cellulose was converted to carboxymethyl cellulose (CMC) by etherification. The extracted cellulose was soaked in a mixed solution of isopropyl alcohol and NaOH solution for 1.5 h. After that, it was reacted with monochloroacetic acid at 70 o C for 1.5 h. The optimum conditions for carboxymethylation were 5 g cellulose, 4.0 g monochloroacetic acid, and 15 ml 25% w/v NaOH and the obtained product had a degree of substitution (DS) of 0.70.
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