BC2.5N异质金刚石在冲击压缩下的沉积机理

T. Komatsu, M. Nomura, Y. Kakudate, S. Fujiwara
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引用次数: 5

摘要

冲击压紧的六方BC2.5N的透射电镜显示,材料形态和成分复杂,大量立方BC2.5N(异质金刚石)、微量非晶态异质金刚石、原子重排的立方BC2.5N、非晶态类金刚石材料和洋葱状杂烯共存。这种产品的多样性表明,液相周围冷却介质的局部不均匀性影响了液相到固相的沉积。对冲击压缩过程的动力学估计也表明了这种机制的可能性。
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Deposition mechanism of BC2.5N heterodiamond under shock compression
Transmission electron microscopy of shock compacted hexagonal BC2.5N indicated the coexistence of morphologically and compositionally complex materials, a large proportion of cubic BC2.5N (heterodiamond), trace amounts of amorphous heterodiamond, atomic-rearranged cubic BC2.5N, an amorphous diamond-like material and onion-like heterofullerene. Such diversities of the products suggested liquid phase-to-solid phase deposition that is affected by the local heterogeneity in the cooling medium surrounding the liquid phase. The possibility of this mechanism was also suggested by kinetic estimations of the shock-compression process.
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