{"title":"一种用于胺的t-丁氧基羰基化的水溶性试剂","authors":"E. Guibe-jampel, M. Wakselman","doi":"10.1039/C29710000267","DOIUrl":null,"url":null,"abstract":"4-Dimethylamino-1-t-butoxycarbonylpyridinium chloride is a stable compound which reacts with amino-acid sodium salts in aqueous solution: at 25 °C the reaction is very fast and BOC = amino-acids (BOC = t-butoxycarbonyl) are isolated in good yields by solvent extraction.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"19 1","pages":"267-267"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"19","resultStr":"{\"title\":\"A water-soluble agent for the t-butoxycarbonylation of amines\",\"authors\":\"E. Guibe-jampel, M. Wakselman\",\"doi\":\"10.1039/C29710000267\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"4-Dimethylamino-1-t-butoxycarbonylpyridinium chloride is a stable compound which reacts with amino-acid sodium salts in aqueous solution: at 25 °C the reaction is very fast and BOC = amino-acids (BOC = t-butoxycarbonyl) are isolated in good yields by solvent extraction.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"19 1\",\"pages\":\"267-267\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"19\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710000267\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000267","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A water-soluble agent for the t-butoxycarbonylation of amines
4-Dimethylamino-1-t-butoxycarbonylpyridinium chloride is a stable compound which reacts with amino-acid sodium salts in aqueous solution: at 25 °C the reaction is very fast and BOC = amino-acids (BOC = t-butoxycarbonyl) are isolated in good yields by solvent extraction.