喀麦隆绿色能源潜力:用于工业应用的棕榈仁油生产的实地调查、理化分析

A. Bong, N. Kor, P. Ndifon
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The paper also reports on the physical and chemical \nproperties of Cameroon palm kernel oil (PKO). Palm kernel oil was extracted \nusing mechanical press and solvent extraction. The palm kernel oil (PKO) from \nCameroon was analyzed by standard physico-chemical methods. Results of the \nphysical measurements show a specific gravity of PKO of 0.92 kg/L, viscosity of \n26.03 cSt and at 5.93 cSt at 40°C and 100°C respectively, viscosity index of \n185, pour point of 20°C, cloud point of 29°C, flash point of 200°C, aniline \npoint of 105°F, diesel index of 23, cetane number of 27 and ASTM (American \nStandards for Testing and Materials) color of less than 2.5. 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摘要

本文报告了一项实地调查,以确定棕榈仁油商业生产用于工业应用的原料的可用性。棕榈仁油生产过程中产生的工业和手工废弃物也作为绿色能源生产的原料(棕榈仁种子)进行了调查。实地研究结果表明,棕榈油加工厂产生的22%的棕榈仁种子(相当于吨废物)被倾倒,而在手工水平上,80%的棕榈仁种子废物被倾倒。对实地研究数据的分析表明,大量废弃棕榈仁种子可用于大规模生产棕榈仁油(PKO),用于绿色能源生产中的理想工业应用。本文还报道了喀麦隆棕榈仁油的理化性质。采用机械压榨法和溶剂萃取法提取棕榈仁油。采用标准理化方法对喀麦隆棕榈仁油进行了分析。物理测量结果表明,PKO的重量为0.92 kg/L,粘度分别为26.03 cSt和5.93 cSt,在40°C和100°C时,粘度指数为185,倾点为20°C,浊点为29°C,闪点为200°C,苯胺点为105°F,柴油指数为23,十六烷值为27,ASTM(美国测试和材料标准)颜色小于2.5。化学分析结果表明,其酸值为17.95 mg KOH/g,游离脂肪酸(FFA)含量为8.98 mg KOH/g,碘值为2.10 mg I2/g,过氧化值为2.10 meq/kg,酯值为123.0 mg KOH/g,羟基值为93.4 mg OH/g,皂化值为140.95 mg KOH/g,硫含量为0.016% w/v,硫含量较低。气相色谱-质谱(GC-MS)分析表明,棕榈仁油主要由各种脂肪酸的甘油酯组成,其中C12 ~ C16脂肪酸残基的比例较高。因此,喀麦隆PKO由于其丰富的物理和化学特性而具有广泛的工业应用。
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Cameroon Green Energy Potentials: Field Survey of Production, Physico-Chemical Analyses of Palm Kernel Oil for Industrial Applications
This paper reports a field survey undertaken to determine the availability of raw material for palm kernel oil commercial production for industrial applications. Both industrial and artisanal wastes from palm kernel oil production were also surveyed as raw material (palm kernel seeds) for green energy production. Results of the field study show that 22% of palm kernel seeds (which represents tons of waste) resulting from palm oil processing plants are dumped while at the artisanal level, 80% of palm kernel seed waste is dumped. Analysis of field study data shows that large amounts of waste palm kernel seeds are available to enable large scale production of palm kernel oil (PKO) for desirable industrial applications in green energy production. The paper also reports on the physical and chemical properties of Cameroon palm kernel oil (PKO). Palm kernel oil was extracted using mechanical press and solvent extraction. The palm kernel oil (PKO) from Cameroon was analyzed by standard physico-chemical methods. Results of the physical measurements show a specific gravity of PKO of 0.92 kg/L, viscosity of 26.03 cSt and at 5.93 cSt at 40°C and 100°C respectively, viscosity index of 185, pour point of 20°C, cloud point of 29°C, flash point of 200°C, aniline point of 105°F, diesel index of 23, cetane number of 27 and ASTM (American Standards for Testing and Materials) color of less than 2.5. Results of chemical analyses showed an acid value of 17.95 mg KOH/g, free fatty acid (FFA) content of 8.98 mg KOH/g, iodine value of 2.10 mg I2/g, peroxide value of 2.10 meq/kg, ester value of 123.0 mg KOH/g, hydroxyl value of 93.4 mg OH/g, saponification value of 140.95 mg KOH/g and a sulfur content of 0.016% w/v, signifying low sulfur content. Gas chromatography-mass spectrometry (GC-MS) showed the palm kernel oil to be predominantly made up of glycerides of various fatty acids with higher proportions of C12 to C16 fatty acid residues. Cameroon PKO therefore has a broad spectrum of industrial applications by virtue of its rich physical and chemical properties.
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