评价天然气催化加工成有价化工产品领域的研究现状和成果

A. Stepanov, L. L. Korobitsyna, A. V. Vosmerikov
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摘要

本文综述了天然气催化转化为有价值的化学产品和燃料的现状。天然气的主要成分是甲烷。甲烷转化过程对社会非常重要,因为天然气和石油一起为我们提供能源、燃料和化学产品。考虑了甲烷直接转化和间接转化的方法。甲烷的直接转化通常被视为现代研究的圣杯,因为甲烷分子非常稳定。综述了合成气、甲醇、乙烯、甲醛、苯等化合物的制备方法。最强调的是甲烷转化的直接过程,即甲烷的脱氢芳构化。考察了催化剂及其制备条件,研究了活性中心的状态,提出了甲烷脱氢芳构化的机理。介绍了催化剂失活的原因和再生的方法。本文综述了天然气多相催化加工领域的最新研究成果。
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Assessment of the current state of research and achievements in the field of catalytic processing of natural gas into valuable chemical products
The review examines the current state of the catalytic conversion of natural gas into valuable chemical products and fuel. The main component of natural gas is methane. Methane conversion processes are of great importance for society because natural gas, along with oil, supplies us with energy, fuel and chemical products. Direct and indirect methods of methane conversion are considered. Direct conversion of methane is often viewed as the holy grail of modern research, since methane molecules are very stable. The review considers the methods of obtaining such compounds as synthesis gas, methanol, ethylene, formaldehyde, benzene, etc. The greatest emphasis is placed on the direct processes of methane conversion, namely on the dehydroaromatization of methane. The catalysts and the conditions for their preparation are considered, the state of active centers is studied, and the mechanism of methane dehydroaromatization is proposed. The reasons for deactivation of the catalysts and methods of their regeneration are also described. This review will help to summarize the latest known achievements in the field of heterogeneous catalysis for natural gas processing.
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