气体在活性炭中的三元吸附动力学

Xijun Hu, Bradley King, Duong D. Do
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引用次数: 16

摘要

收集了不同浓度组合、温度和粒径下乙烷(轻组分)、丙烷(中间组分)和正丁烷在活性炭中的三元吸附动力学实验。研究了这些参数对三元吸附动力学的影响。所有实验数据与Hu和Do (AIChE J(1993) 39 1628)最近提出的仅使用单组分平衡和传质参数的多组分非均质大孔、表面和微孔扩散(HMSMD)模型的预测结果进行了比较。该模型能较准确地预测乙烷、丙烷和正丁烷的吸附速率,但在计算三元平衡丙烷的吸附量时误差较小。
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Ternary adsorption kinetics of gases in activated carbon

Ternary adsorption kinetic experiments of ethane (light species), propane (intermediate species) and n-butane in activated carbon are collected under various concentration combinations, temperatures and particle sizes. The effects of these parameters on the ternary adsorption dynamics are investigated. All the experimental data are compared with the predictions by a multicomponent heterogeneous macropore, surface and micropore diffusion (HMSMD) model recently proposed by Hu and Do (AIChE J (1993) 39 1628) using only single-component equilibrium and mass transfer parameters. The model can accurately predict the adsorption rates of ethane, propane and n-butane, but a small error in the calculation of the adsorbed amount of propane at ternary equilibrium is observed.

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