涉及O,O供体环境的氧钒(IV)配合物与生物无机和医学相关

R. Maurya, H. Singh
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引用次数: 4

摘要

摘要:通过与五水硫酸钒的相互作用,合成了六种新的氧钒(IV)混合配体配合物[VO(L1)(L2)(H2O)],其中L1H = 4‐丁基‐3‐甲基‐1‐苯基‐2‐吡唑啉‐5‐1 (bmppH), L2H =乙酰乙酰苯胺(aaH), o‐乙酰乙酰甲酰(o‐aatdH), o‐乙酰乙酰甲酰(o‐aansH),甲基乙酰乙酸酯(macacH),乙基乙酰乙酸酯(eacacH)或二苯甲酰甲烷(dbmH)。对配合物进行了表征,并提出了配合物的结构。对其中一种具有代表性的化合物进行了三维分子建模和分析。
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Oxovanadium(IV) Complexes Involving O,O‐Donor Environment of Bioinorganic and Medicinal Relevance
Abstract Six new mixed‐ligands complexes of oxovanadium(IV) of the general composition [VO(L1)(L2)(H2O)], where L1H = 4‐butyryl‐3‐methyl‐1‐phenyl‐2‐pyrazoline‐5‐one (bmppH), L2H = acetoacetanilide (aaH), o‐acetoacetotoluidide (o‐aatdH), o‐acetoacetanisidide (o‐aansH), methylacetoacetate (macacH), ethylacetoacetate (eacacH) or dibenzoylmethane (dbmH), have been synthesized by the interaction of these ligands with vanadyl sulfate pentahydrate. The complexes have been characterized and structures have been proposed for these complexes. The 3D molecular modeling and analysis have been carried out for one of the representative compounds.
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