{"title":"涉及O,O供体环境的氧钒(IV)配合物与生物无机和医学相关","authors":"R. Maurya, H. Singh","doi":"10.1081/SIM-120028301","DOIUrl":null,"url":null,"abstract":"Abstract Six new mixed‐ligands complexes of oxovanadium(IV) of the general composition [VO(L1)(L2)(H2O)], where L1H = 4‐butyryl‐3‐methyl‐1‐phenyl‐2‐pyrazoline‐5‐one (bmppH), L2H = acetoacetanilide (aaH), o‐acetoacetotoluidide (o‐aatdH), o‐acetoacetanisidide (o‐aansH), methylacetoacetate (macacH), ethylacetoacetate (eacacH) or dibenzoylmethane (dbmH), have been synthesized by the interaction of these ligands with vanadyl sulfate pentahydrate. The complexes have been characterized and structures have been proposed for these complexes. The 3D molecular modeling and analysis have been carried out for one of the representative compounds.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":"37 1","pages":"269 - 290"},"PeriodicalIF":0.0000,"publicationDate":"2004-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Oxovanadium(IV) Complexes Involving O,O‐Donor Environment of Bioinorganic and Medicinal Relevance\",\"authors\":\"R. Maurya, H. Singh\",\"doi\":\"10.1081/SIM-120028301\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Six new mixed‐ligands complexes of oxovanadium(IV) of the general composition [VO(L1)(L2)(H2O)], where L1H = 4‐butyryl‐3‐methyl‐1‐phenyl‐2‐pyrazoline‐5‐one (bmppH), L2H = acetoacetanilide (aaH), o‐acetoacetotoluidide (o‐aatdH), o‐acetoacetanisidide (o‐aansH), methylacetoacetate (macacH), ethylacetoacetate (eacacH) or dibenzoylmethane (dbmH), have been synthesized by the interaction of these ligands with vanadyl sulfate pentahydrate. The complexes have been characterized and structures have been proposed for these complexes. The 3D molecular modeling and analysis have been carried out for one of the representative compounds.\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":\"37 1\",\"pages\":\"269 - 290\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-120028301\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-120028301","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Oxovanadium(IV) Complexes Involving O,O‐Donor Environment of Bioinorganic and Medicinal Relevance
Abstract Six new mixed‐ligands complexes of oxovanadium(IV) of the general composition [VO(L1)(L2)(H2O)], where L1H = 4‐butyryl‐3‐methyl‐1‐phenyl‐2‐pyrazoline‐5‐one (bmppH), L2H = acetoacetanilide (aaH), o‐acetoacetotoluidide (o‐aatdH), o‐acetoacetanisidide (o‐aansH), methylacetoacetate (macacH), ethylacetoacetate (eacacH) or dibenzoylmethane (dbmH), have been synthesized by the interaction of these ligands with vanadyl sulfate pentahydrate. The complexes have been characterized and structures have been proposed for these complexes. The 3D molecular modeling and analysis have been carried out for one of the representative compounds.