回收印刷聚丙烯标签和聚烯烃瓶盖作为化学发泡剂生产泡沫制品

IF 3.2 4区 工程技术 Q2 CHEMISTRY, APPLIED Journal of Cellular Plastics Pub Date : 2020-09-30 DOI:10.1177/0021955X20959302
J. Guillén-Mallette, P. Gonzalez-Chi, RH Cruz-Estrada, RN Miranda-Flores y, Ma Rivero-Ayala
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引用次数: 2

摘要

研究了回收印刷聚丙烯(PP)标签和印刷聚烯烃(PO)瓶盖作为化学发泡剂生产泡沫制品。采用实验田口L16设计,涉及七个实验变量:滑石含量和螺杆角速度,在四个实验水平;挤出温度分布和挤出配方,分为三个层次;并且,类型标签的洗涤工艺,使用金属网和类型标签的干燥工艺,分两个层次。作为控制变量,细胞的形态和泡沫产品的密度被利用。标签/瓶盖混合物由21%的印刷PP标签和79%的印刷聚烯烃瓶盖组成。熔融聚合物中存在的部分油墨标签颜料和一些低分子量材料的极性基团在PP加工温度下被部分分解,这有助于挤出泡沫的细胞形成和生长。由于回收的PP瓶盖和标签中存在高密度聚乙烯(HDPE)和EVA,标签/瓶盖混合物产生了面向挤压方向的大椭球状和细长的细胞(740µm)。影响泡沫密度的主要因素是螺杆角速度和温度,泡沫细胞形态主要受基体结晶度和熔体强度的影响。
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Recycling printed polypropylene labels and polyolefins caps as chemical foaming agent to produce foam products
Recycling printed polypropylene (PP) labels and printed polyolefins (PO) caps as a chemical foaming agent to produce foam products is studied. An experimental Taguchi L16 design with seven experimental variables involved is used: talc content and screw angular velocity, at four experimental levels; extrusion temperature profile and extruded formulations, at three levels; and, type of label washing process, the use of metal mesh and the type of label drying process, at two levels. As control variables, the morphology of the cells and the density of the foamed products are utilized. The labels/caps mixture was composed of 21% printed PP labels and 79% printed polyolefin caps. Part of the pigments from the ink labels and some polar groups of low-molecular-weight materials present in the molten polymer were partially decomposed at the PP processing temperatures, which contributes to the cell formation and growth of the extruded foams. The labels/caps mixture generated large ellipsoidal and elongated cells (740 µm) oriented in the extrusion direction because of the presence of high density polyethylene (HDPE) and EVA in the recycled PP caps and labels. The experimental factors that influenced the foam density were the screw angular velocity and temperature, and the cell morphology depended on the matrix crystallinity and melt strength.
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来源期刊
Journal of Cellular Plastics
Journal of Cellular Plastics 工程技术-高分子科学
CiteScore
5.00
自引率
16.00%
发文量
19
审稿时长
3 months
期刊介绍: The Journal of Cellular Plastics is a fully peer reviewed international journal that publishes original research and review articles covering the latest advances in foamed plastics technology.
期刊最新文献
I-WP geometry structural assessment: A theoretical, experimental, and numerical analysis Foam density measurement using a 3D scanner Effect of temperature on the mechanical behavior of pvc foams Preparation and energy absorption of flexible polyurethane foam with hollow glass microsphere A review on the mechanical behaviour of microcellular and nanocellular polymeric foams: What is the effect of the cell size reduction?
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