[C12H14N2][Fe(CN)5(NO)]⋅5H2O杂化盐的合成及非线性光学研究

IF 2.9 4区物理与天体物理 Q2 OPTICS Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-02-17 DOI:10.1142/s0218863522500151

M. Zidan, M. Al-Ktaifani, M. S. El-daher, A. Allahham, A. Ghanem

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引用次数: 0

摘要

合成了新制备的杂化盐1,1 ' -(乙烯-1,2-二基)五氰硝基高铁酸二吡啶(II)五水化合物。然后，用不同的光谱方法对其进行了表征。采用简单的[公式:见文]-连续波二极管激光辐射([公式:见文][公式:见文]nm)扫描技术研究了新化合物的非线性光学性质。此外，采用泵浦/探头配置的扫描技术观察了交叉相位调制(XPM)现象。对新的实验数据进行理论拟合，计算了包括非线性折射率在内的三阶非线性光学参数，约为[公式:见文]cm2/W。这种分子被认为是未来光电器件中很有前途的候选分子。

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Synthesis and nonlinear optical study of the hybrid salt: [C12H14N2][Fe(CN)5(NO)]⋅5H2O

The new prepared hybrid salt 1,1’-(Ethylene-1,2-diyl)dipyridinium pentacyanidonitrosoferrate(II) pentahydrate was synthesized. Then, it was characterized using different spectroscopic methods. The nonlinear optical properties of the new compound were investigated using the simple [Formula: see text]-scan technique with a CW diode laser radiation ([Formula: see text][Formula: see text]nm). Also, the [Formula: see text]-scan technique with pump/probe configuration was utilized to observe the Cross Phase Modulation (XPM) phenomena. Theoretical fit to the new experimental data was performed to calculate the third order nonlinear optical parameters including the nonlinear refractive index, which is about [Formula: see text][Formula: see text]cm2/W. This kind of molecule is considered to be promising candidate for using in future optoelectronic devices.

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来源期刊

Journal of Nonlinear Optical Physics & Materials 物理-光学

CiteScore

3.00

自引率

48.10%

发文量

审稿时长

3 months

期刊介绍： This journal is devoted to the rapidly advancing research and development in the field of nonlinear interactions of light with matter. Topics of interest include, but are not limited to, nonlinear optical materials, metamaterials and plasmonics, nano-photonic structures, stimulated scatterings, harmonic generations, wave mixing, real time holography, guided waves and solitons, bistabilities, instabilities and nonlinear dynamics, and their applications in laser and coherent lightwave amplification, guiding, switching, modulation, communication and information processing. Original papers, comprehensive reviews and rapid communications reporting original theories and observations are sought for in these and related areas. This journal will also publish proceedings of important international meetings and workshops. It is intended for graduate students, scientists and researchers in academic, industrial and government research institutions.