A. Bravo, F. Fontana, G. Fronza, A. Mele, F. Minisci
{"title":"氧化过程中烷烃和烷基自由基诱导二甲基二氧环烷均解。分子氧和自由基抑制剂的显著作用","authors":"A. Bravo, F. Fontana, G. Fronza, A. Mele, F. Minisci","doi":"10.1039/C39950001573","DOIUrl":null,"url":null,"abstract":"The oxidation of alkanes by dimethyldioxirane is dramatically affected by the presence of molecular oxygen and radical inhibitors, supporting the hypothesis of a free-radical mechanism for these extraordinarily selective reactions; the factors affecting the free-radical selectivity are suggested.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"103 1","pages":"1573-1574"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"13","resultStr":"{\"title\":\"Induced homolysis of dimethyldioxirane by alkanes and alkyl radicals in oxidation processes. The dramatic role of molecular oxygen and radical inhibitors\",\"authors\":\"A. Bravo, F. Fontana, G. Fronza, A. Mele, F. Minisci\",\"doi\":\"10.1039/C39950001573\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The oxidation of alkanes by dimethyldioxirane is dramatically affected by the presence of molecular oxygen and radical inhibitors, supporting the hypothesis of a free-radical mechanism for these extraordinarily selective reactions; the factors affecting the free-radical selectivity are suggested.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"103 1\",\"pages\":\"1573-1574\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"13\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001573\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001573","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Induced homolysis of dimethyldioxirane by alkanes and alkyl radicals in oxidation processes. The dramatic role of molecular oxygen and radical inhibitors
The oxidation of alkanes by dimethyldioxirane is dramatically affected by the presence of molecular oxygen and radical inhibitors, supporting the hypothesis of a free-radical mechanism for these extraordinarily selective reactions; the factors affecting the free-radical selectivity are suggested.