生物萃取还原氧化石墨烯在壳聚糖生物聚合物结晶动力学中的作用

Solomon L. Joseph, Agumba O. John, F. M. Keheze
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摘要

碳纳米材料由于其可调谐的特性,近年来吸引了广泛的科学应用。这些新型材料作为最好的填料,由于其高强度、导热性和导电性,可以提供实质性的好处。随着它们作为块状材料的广泛应用,当它们作为填料应用于聚合物基体时,它们产生了新的有前途的材料,它们的性能可以调整以适应特定的应用。除了这些新型纳米复合材料的发展,还存在一些必须完全克服的挑战,以探索碳基纳米复合材料的应用潜力。还原氧化石墨烯是当前技术发展中备受关注的碳衍生物之一,近年来在电子工业的超级电容器中有了新的应用。勘探的限制因素是负担能力。为了充分实现这些石墨烯基纳米材料的潜在应用,必须设计出新的和负担得起的来源。在本研究中,从当地可利用的生物废弃物中提取还原氧化石墨烯和生物聚合物壳聚糖。以50%还原氧化石墨烯与壳聚糖的比例制备了纳米复合材料。然后采用自旋镀膜法制备薄膜。对制备的薄膜进行形态学分析。结果表明,还原氧化石墨烯诱导壳聚糖结晶,形成树突状结构。纤维素纳米晶体因此显示出温度依赖的正单轴双折射
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The Role of Bio-Extracted Reduced Graphene Oxide in the Crystallization Kinetics of Chitosan Bio-Polymer
Carbon nanomaterials have recently attracted wide scientific applications due to their tunable properties. These novel materials act as best fillers that can provide substantial benefits due to their high strength, thermal conductivity, and electrical conductivities. With their huge applications as bulk materials, when implemented in polymer matrix as fillers, they give rise to new promising materials with which their properties can be tuned to suit a particular application. Besides the development of these new nanocomposite materials, there exist some challenges which must be fully surpassed to explore the potentiality of application of carbon-based nanocomposites. Reduced graphene oxide is one of the carbon derivatives which has attracted the current advancement in technology, and recently, it found its new applications in super capacitors used in electronic industries. The limiting factor for its exploration is the affordability. New and affordable sources of these graphene-based nanomaterial have to be devised, for fully realization of their potential applications. In this study, reduced graphene oxide and the bio-polymer chitosan were extracted from the locally available bio waste materials. Nanocomposites were prepared at 50% rGO: chitosan ratio. The films were then prepared by spin coating method. Prepared films were subjected to morphological analysis. From the results, it was observed that rGO induced chitosan crystallization, which led to formation of dendritic structures. Cellulose nanocrystals have thus displayed temperature dependent positive uniaxial birefringence
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