{"title":"三(三甲基硅烷基)硅烷","authors":"B. Giese, J. Dickhaut, C. Chatgilialoglu","doi":"10.1002/9780470842898.RT420.PUB2","DOIUrl":null,"url":null,"abstract":"[1873-77-4] C9H28Si4 (MW 248.73) \n \n \n \n \n \nInChI = 1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3 \n \n \n \nInChIKey = SQMFULTZZQBFBM-UHFFFAOYSA-N \n \n \n \n(mediator of radical reactions;1, 2 nontoxic substitute for tri-n-butylstannane in radical reactions; slower hydrogen donor than tri-n-butylstannane3) \n \n \n \nAlternatives names: TTmss(Tms)3SiH \n \n \n \nPhysical Data: bp 82–84 °C/12 mmHg; d 0.806 g cm−3; n20D 1.489. \n \n \n \nSolubility: sol pentane, ether, toluene, THF; modestly sol acetone, acetonitrile; insol H2O; decomposes rapidly in methanol and other alcohols. \n \n \n \nForm Supplied in: colorless liquid; commercially available. \n \n \n \nPreparative Method: easy to synthesize.4 \n \n \n \nHandling, Storage, and Precautions: is slightly sensitive to oxygen and should be stored under nitrogen.5 It showed no toxicity in several biological test systems.6","PeriodicalId":11669,"journal":{"name":"Encyclopedia of Reagents for Organic Synthesis","volume":"56 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2003-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Tris(trimethylsilyl)silane\",\"authors\":\"B. Giese, J. Dickhaut, C. Chatgilialoglu\",\"doi\":\"10.1002/9780470842898.RT420.PUB2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"[1873-77-4] C9H28Si4 (MW 248.73) \\n \\n \\n \\n \\n \\nInChI = 1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3 \\n \\n \\n \\nInChIKey = SQMFULTZZQBFBM-UHFFFAOYSA-N \\n \\n \\n \\n(mediator of radical reactions;1, 2 nontoxic substitute for tri-n-butylstannane in radical reactions; slower hydrogen donor than tri-n-butylstannane3) \\n \\n \\n \\nAlternatives names: TTmss(Tms)3SiH \\n \\n \\n \\nPhysical Data: bp 82–84 °C/12 mmHg; d 0.806 g cm−3; n20D 1.489. \\n \\n \\n \\nSolubility: sol pentane, ether, toluene, THF; modestly sol acetone, acetonitrile; insol H2O; decomposes rapidly in methanol and other alcohols. \\n \\n \\n \\nForm Supplied in: colorless liquid; commercially available. \\n \\n \\n \\nPreparative Method: easy to synthesize.4 \\n \\n \\n \\nHandling, Storage, and Precautions: is slightly sensitive to oxygen and should be stored under nitrogen.5 It showed no toxicity in several biological test systems.6\",\"PeriodicalId\":11669,\"journal\":{\"name\":\"Encyclopedia of Reagents for Organic Synthesis\",\"volume\":\"56 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2003-04-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Encyclopedia of Reagents for Organic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/9780470842898.RT420.PUB2\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Encyclopedia of Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780470842898.RT420.PUB2","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
[1873-77-4] C9H28Si4 (MW 248.73)
InChI = 1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3
InChIKey = SQMFULTZZQBFBM-UHFFFAOYSA-N
(mediator of radical reactions;1, 2 nontoxic substitute for tri-n-butylstannane in radical reactions; slower hydrogen donor than tri-n-butylstannane3)
Alternatives names: TTmss(Tms)3SiH
Physical Data: bp 82–84 °C/12 mmHg; d 0.806 g cm−3; n20D 1.489.
Solubility: sol pentane, ether, toluene, THF; modestly sol acetone, acetonitrile; insol H2O; decomposes rapidly in methanol and other alcohols.
Form Supplied in: colorless liquid; commercially available.
Preparative Method: easy to synthesize.4
Handling, Storage, and Precautions: is slightly sensitive to oxygen and should be stored under nitrogen.5 It showed no toxicity in several biological test systems.6
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