{"title":"辐射mechanisms-VIII。硼氢化物离子在水溶液中的放射性溶解。一项esr研究","authors":"Martyn C.R. Symons","doi":"10.1016/0020-7055(76)90085-1","DOIUrl":null,"url":null,"abstract":"<div><p>Radiolysis of frozen aqueous or methanolic glasses containing sodium borohydride gave E.S.R. features characteristic of ·BH<sub>3</sub><sup>−</sup> as the major radical product. These radicals were strongly associated with the solvent lattice in contrast with their behaviour in the parent salt. Additional E.S.R. features separated by <em>ca</em>. 200 G are assigned to BH<sub>4</sub>, but since this spectrum could never be obtained in the absence of the intense BH<sub>3</sub><sup>−</sup> features, this assignment is tentative.</p></div>","PeriodicalId":100688,"journal":{"name":"International Journal for Radiation Physics and Chemistry","volume":"8 3","pages":"Pages 381-385"},"PeriodicalIF":0.0000,"publicationDate":"1976-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7055(76)90085-1","citationCount":"2","resultStr":"{\"title\":\"Radiation mechanisms—VIII. Radiolysis of borohydride ions in aqueous solutions. An E.S.R. study\",\"authors\":\"Martyn C.R. Symons\",\"doi\":\"10.1016/0020-7055(76)90085-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Radiolysis of frozen aqueous or methanolic glasses containing sodium borohydride gave E.S.R. features characteristic of ·BH<sub>3</sub><sup>−</sup> as the major radical product. These radicals were strongly associated with the solvent lattice in contrast with their behaviour in the parent salt. Additional E.S.R. features separated by <em>ca</em>. 200 G are assigned to BH<sub>4</sub>, but since this spectrum could never be obtained in the absence of the intense BH<sub>3</sub><sup>−</sup> features, this assignment is tentative.</p></div>\",\"PeriodicalId\":100688,\"journal\":{\"name\":\"International Journal for Radiation Physics and Chemistry\",\"volume\":\"8 3\",\"pages\":\"Pages 381-385\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1976-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7055(76)90085-1\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal for Radiation Physics and Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020705576900851\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal for Radiation Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020705576900851","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Radiation mechanisms—VIII. Radiolysis of borohydride ions in aqueous solutions. An E.S.R. study
Radiolysis of frozen aqueous or methanolic glasses containing sodium borohydride gave E.S.R. features characteristic of ·BH3− as the major radical product. These radicals were strongly associated with the solvent lattice in contrast with their behaviour in the parent salt. Additional E.S.R. features separated by ca. 200 G are assigned to BH4, but since this spectrum could never be obtained in the absence of the intense BH3− features, this assignment is tentative.
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