壳聚糖分离及其在降低井筒水中金属离子含量中的应用

Yulida Amri, R. Fajri, Matius Stefanus Batu
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引用次数: 2

摘要

白虾壳废弃物等潜在水源可作为壳聚糖的来源。壳聚糖对金属离子的吸附能力使其成为一种环保的水处理吸附剂。在本研究中,壳聚糖经过脱矿、脱蛋白、脱色和脱乙酰等几个步骤进行分离。壳聚糖得率为17.73%。红外光谱(FTIR)表征表明在3355 cm -1处的吸收表明存在胺(- nh2)和羟基(-OH)基团。1642 cm -1处羰基(-C=O)的吸收消失,而1590 cm -1处游离胺基(- nh2)的吸收增加,表明脱乙酰成功,脱乙酰度(DD)为78%。由于壳聚糖在井筒水中的铁浓度较低,对井筒水的颜色变化和铁含量降低没有影响。然而,壳聚糖会降低水的pH值和锰的含量。方差分析和DMRT检验结果显示,不同质量的壳聚糖效果不同。壳聚糖的加入量越大,锰的含量越低。
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CHITOSAN ISOLATION AND ITS APPLICATION TO REDUCE THE CONTENT OF METAL IONS IN WELLBORE WATER
Potential water sources such as white shrimp shell waste (Penaeus merguiensis) can be used as a source of chitosan. Chitosan can be applied as an environmentally friendly adsorbent for water treatment because of its ability to adsorb metal ions. In this study, chitosan was isolated through several stages such as demineralization, deproteination, decolourization and deacetylation. The yield of chitosan obtained from this study was 17.73%. Characterization by infrared spectroscopy (FTIR) showed the absorption at 3355 cm -1 indicating the presence of amine (-NH 2 ) and hydroxyl (-OH) groups. The absorption of the carbonyl group (-C=O) at 1642 cm -1 disappeared while the absorption of the free amine group (-NH 2 ) at 1590 cm -1 increased indicating the successful deacetylation with a degree of deacetylation (DD) 78%. Application of chitosan in wellbore water did not affect on colour change and decreasing of iron (Fe) content due to low concentration of iron (Fe). However, chitosan can reduce the pH value of water and manganese (Mn) content. The results of ANOVA and DMRT test at 0.05 significance level showed that chitosan with various mass had different effects. The more the mass of chitosan added, the higher the content of manganese (Mn) will decrease.
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