{"title":"广泛应用的缩合合成氨基膦途径的深入分析:氨基合成物(氯膦)(NC4H8N)[P(i-Pr2N)Cl]的合成与光谱表征","authors":"J. Gopalakrishnan","doi":"10.1080/15533174.2015.1040163","DOIUrl":null,"url":null,"abstract":"Aminophosphines are useful as ligands and the most convenient method to synthesize is the condensation route that is straightforward, simple and easy to execute and get the products. RxPClz (x = 0–2, y = 1–3) and amines are widely used as phosphorus and nitrogen substrates. Vast examples such as Phx(R2N)yPClz [x < 3; y > 0; z < 3] are available in the literature which used condensation route. A deep analysis was carried out on this route and the author analyzes various parameters that affect product formation, purity, and yield. Using the optimized conditions, (NC4H8N)[P(i-Pr2N)Cl]2 was prepared and spectrally characterized.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A Deep Analysis on Widely Used Condensation Route for Preparing Aminophosphines: Synthesis and Spectral Characterization of an Aminobis(chlorophosphine), (NC4H8N)[P(i-Pr2N)Cl]2\",\"authors\":\"J. Gopalakrishnan\",\"doi\":\"10.1080/15533174.2015.1040163\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Aminophosphines are useful as ligands and the most convenient method to synthesize is the condensation route that is straightforward, simple and easy to execute and get the products. RxPClz (x = 0–2, y = 1–3) and amines are widely used as phosphorus and nitrogen substrates. Vast examples such as Phx(R2N)yPClz [x < 3; y > 0; z < 3] are available in the literature which used condensation route. A deep analysis was carried out on this route and the author analyzes various parameters that affect product formation, purity, and yield. Using the optimized conditions, (NC4H8N)[P(i-Pr2N)Cl]2 was prepared and spectrally characterized.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1040163\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1040163","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Deep Analysis on Widely Used Condensation Route for Preparing Aminophosphines: Synthesis and Spectral Characterization of an Aminobis(chlorophosphine), (NC4H8N)[P(i-Pr2N)Cl]2
Aminophosphines are useful as ligands and the most convenient method to synthesize is the condensation route that is straightforward, simple and easy to execute and get the products. RxPClz (x = 0–2, y = 1–3) and amines are widely used as phosphorus and nitrogen substrates. Vast examples such as Phx(R2N)yPClz [x < 3; y > 0; z < 3] are available in the literature which used condensation route. A deep analysis was carried out on this route and the author analyzes various parameters that affect product formation, purity, and yield. Using the optimized conditions, (NC4H8N)[P(i-Pr2N)Cl]2 was prepared and spectrally characterized.
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