低温合成功能纳米碳的绿色途径

Gregorio Guadalupe Carbajal Arízaga , José Guadalupe Quiñones Galván , Alesandro Bail , Andrea Lizeth Pérez González , Citlali Pereyra Nuñez , Miguel Ángel López Álvarez
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引用次数: 0

摘要

碳纳米颗粒已经证明了它们在开发具有先进应用的材料方面的潜力,其中利用了它们的发光和生物相容性。在寻找生产这些纳米颗粒的可持续方法的过程中,已经使用了天然碳源,如植物和动物产品及其副产品。然而,现有的方法仍然是在高温、高压和长反应时间下进行的。本文提出了一种以番茄提取物为碳源,在最高60℃的常压下沉淀和煅烧合成纳米碳的方法。这是报道的最低的煅烧温度,有助于建立更环保的合成路线。检测到的这些粒子的荧光覆盖了可见光谱的整个区域。发射强度对锌离子敏感,表明这种绿色方法在检测重金属方面产生了与传统方法相似的有用颗粒。此外,这些粒子的水溶液在红光照射下是光热的,这也显示了它们在生物医学发展中的用途。因此,这种极低温的绿色合成有助于改进绿色方法,促进先进功能材料的可持续发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Green approach to synthesize functional carbon nanoparticles at low temperature

Carbon nanoparticles have demonstrated their potential to develop materials with advanced applications in which their luminescence and biocompatibility are exploited. In the search for sustainable methods to produce these nanoparticles, natural carbon sources such as plant- and animal-based products and by-products have been used. However, the existing procedures are still performed with high temperature, high pressure, and long reaction times. This report proposes a method to synthesize carbon nanoparticles using a tomato extract as the carbon source, followed by precipitation and calcination at a maximum of 60 °C under atmospheric pressure. This calcination temperature is the lowest reported and contributes to establishing a greener synthesis route. The detected fluorescence of these particles covers the entire region of the visible spectrum. The emission intensity is sensitive to zinc cations, demonstrating that this green method produces useful particles in detecting heavy metals similar to those reported by traditional methods. Furthermore, the aqueous solutions of these particles are photothermic when they are irradiated with red light, also showing their usefulness in biomedical developments. Therefore, this green synthesis at a very low temperature contributes to improving the green methods and boosts the sustainable development of advanced functional materials.

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Erratum to Green approach to synthesize functional carbon nanoparticles at low temperature [Sustainable Chemistry for Climate Action (2022) 100002] Erratum to Developments in the investigation of nitrogen and oxygen stable isotopes in atmospheric nitrate [Sustainable Chemistry for Climate Action (2022) 100003] Erratum to “Conversion of furfuryl alcohol into alkyl¿levulinates using solid acid catalysts” [Sustainable Chemistry for Climate Action (2022) 100004] Advances and challenges in pretreatment technologies for bioethanol production: A comprehensive review Pretreatment of lignocellulosic biomass waste mixtures using a low-cost ionic liquid
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