基于聚合物/MWCNT和聚合物/G纳米复合材料的丝网印刷电极用于先进的气体传感应用

A. Grozdanov, Iva Dimitrievska, P. Paunović, A. Petrovski
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引用次数: 0

摘要

本文报道了基于聚合物/碳纳米结构(多壁碳纳米管- MWCNT和石墨烯- G)的丝网印刷电极(SPE)在气体传感器中的应用结果。商用聚乙烯采用导电聚合物聚偏氟乙烯- PVDF和生物相容性聚乙二醇- PEG等聚合物进行改性。改性SPEs在不同浓度的氨蒸气中进行测试:3、6.2、12.5和25% (wt.)。传感器测试是通过监测电极电阻的变化来进行的。利用扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR)在ATR模式下对传感电极进行了物理表征。CNT/PEG和CNT/ PVDF改性后的表面形貌表现了氨对纳米复合层表面的影响。氨溶液在修饰过的表面上产生强烈的作用,在均匀的结构和非常小的氧化物纳米棒中形成沟槽。
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Screen printed electrodes based on polymer/MWCNT and polymer/G nanocomposite for advanced gas sensing application
This paper reported the results of application of screen printed electrodes (SPE) based on polymer/carbon nanostructures (multi wall carbon nanotubes – MWCNT and grapheme – G) for gas sensors. Commercial SPEs were modified by polymers such as conductive polymer Poly Vinylidene Fluorid – PVDF and biocompatible Poly Ethylene Glycol – PEG. Modified SPEs were tested in ammonia vapors with different concentration: 3, 6.2, 12.5 and 25% (wt.). Sensor-testing was performed by monitoring the change in the electrical resistance of the electrodes. The physical characterization of the sensing electrodes was performed by Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) in ATR mode. The surface morphology of CNT/PEG and CNT/ PVDF modifications, after coating with 25% NH3, expressed the effects of ammonia on the surface of the nanocomposite layer. The ammonia solution acts aggressively on the modified surface, causing furrows to form in the uniform structure and very small nanorods of oxides.
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