关于双组分核磁共振弛豫

H. Winkler , A. Gutsze
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引用次数: 15

摘要

对于双组分弛豫行为,每个组分的时间常数(表观弛豫时间)和指数前因子(表观概率)是实际弛豫时间、总体分数(实际概率)和涉及两个区域的寿命的复杂函数,在这两个区域之间发生分子、原子核或自旋交换。对齐默尔曼和布里廷的理论处理进行了概述,并详细地描绘了视量作为实量的函数,反之亦然。
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On two-component NMR relaxation

For two-component relaxation behaviour the time constant (apparent relaxation time) and the preexponential factor (apparent probability) of each of the components are complicated functions of the real relaxation times, the population fractions (real probabilities) and the lifetimes referring to two regions, between which an exchange of molecules, nuclei or spins occurs. The theoretical treatment of Zimmerman and Brittin is sketched and the apparent quantities as functions of the real quantities and vice versa are plotted in detail.

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