合成方法对白色LED荧光粉材料Sr3Y1.95Ge3O12: 0.05Eu3+ (SYGO: Eu3+)特性的影响

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摘要

采用固相反应、共沉淀法和溶胶-凝胶法制备了Sr3Y1.95Ge3O12:0.05Eu3+ (SYGO: Eu3+)石榴石结构。研究了样品的形态结构和光致发光性能。荧光粉的形态和粒径随制备的不同而变化。根据x射线衍射图测量,溶胶-凝胶样品只表现出SYGO: Eu3+的特征,表现出属于Ia3d(230)空间群的立方结构。相比于共沉淀和固相反应两种方法,溶胶-凝胶法更具有单相结构。在395 nm激发波长下,制备的样品均发出红光,最大发射峰位于612 nm,对应于SYGO主晶格中Eu3+离子的5D0→7F2跃迁。溶胶-凝胶法制备的SYGO: Eu3+样品的色坐标分别为x = 0.65和y = 0.35。因此,基于溶胶-凝胶法合成的SYGO: Eu3+是一种很有前途的白光LED荧光粉。
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Effects of Synthesis Methods on the Characteristics of Material Sr3Y1.95Ge3O12: 0.05Eu3+ (SYGO: Eu3+) for White LED Phosphors Applications
Solid-state reaction, co-precipitation, and sol-gel procedures were used to synthesize the Sr3Y1.95Ge3O12:0.05Eu3+ (SYGO: Eu3+) garnet structure. The morphological structure and photoluminescence properties of the samples were studied. Phosphors have morphologies and particle sizes that vary depending on the preparation. According to the X-ray diffraction pattern measurement, the sol-gel sample only appeared to exhibit the SYGO: Eu3+ characteristic that it shows the cubic structure belonging to the Ia3d (230) space group. In comparison to the two approaches of co-precipitation and solid-phase reaction, the sol-gel method has a more single-phase structure. Under the excitation wavelength of 395 nm, all produced samples emitted red light, with the greatest emission peak at 612 nm, corresponding to the 5D0→7F2 transition of Eu3+ ions in the SYGO host lattice. The color coordinates of the sample SYGO: Eu3+ fabricated by the sol-gel method are x = 0.65 and y = 0.35. Therefore, the SYGO: Eu3+ based on sol-gel method’s synthesis is a promising phosphor for the application of White LED.
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