{"title":"用多金属氧酸盐衍生的疏水二氧化硅颗粒作为催化剂在水中氧化烯烃","authors":"R. Neumann, H. Miller","doi":"10.1039/C39950002277","DOIUrl":null,"url":null,"abstract":"An insoluble catalytic assembly consisting of a silicate xerogel covalently modified with phenyl groups and quaternary ammonium–polyoxometalate ion pairs was used to catalyse the oxidation of alkenes with 30% aqueous hydrogen peroxide in the absence of an organic solvent.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"44","resultStr":"{\"title\":\"Alkene oxidation in water using hydrophobic silica particles derivatized with polyoxometalates as catalysts\",\"authors\":\"R. Neumann, H. Miller\",\"doi\":\"10.1039/C39950002277\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An insoluble catalytic assembly consisting of a silicate xerogel covalently modified with phenyl groups and quaternary ammonium–polyoxometalate ion pairs was used to catalyse the oxidation of alkenes with 30% aqueous hydrogen peroxide in the absence of an organic solvent.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"44\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950002277\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950002277","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Alkene oxidation in water using hydrophobic silica particles derivatized with polyoxometalates as catalysts
An insoluble catalytic assembly consisting of a silicate xerogel covalently modified with phenyl groups and quaternary ammonium–polyoxometalate ion pairs was used to catalyse the oxidation of alkenes with 30% aqueous hydrogen peroxide in the absence of an organic solvent.
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