选择性电子受体化合物的合成

L. Troisi, C. Citti, C. Granito, S. Perrone, A. Ciccarese, S. Bettini, G. Giancane, A. Troisi
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引用次数: 1

摘要

设计合成了新型苝单亚胺、二亚胺和双二亚胺。对这些化合物的合成也进行了详细的研究,以突出获得一类特定分子的关键因素。具体地说,人们的注意力集中在中间体苝单亚胺的合成上,这是许多难以获得的分子的非常有用的前体。此外,还开发了两种合成途径来获得不同取代的双二亚胺。预计这些最终化合物将模仿富勒烯衍生物的优异电子受体性质,它们可以用作形成3D半导体材料的基石。
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Synthesis of Alternative Electron Acceptor Compounds
New perylene monoimides, diimides and bis-diimides have been designed and synthetized. A detailed investigation of the synthesis of these compounds has also been performed in order to highlight the crucial factors for obtaining a specific class of molecules. Specifically, the attention has been focused on the synthesis of the intermediate perylene monoimides which are very useful precursors for many molecules difficult to obtain. Furthemore, two synthetic pathways have been developed for obtaining the bis-diimides variously substituted. These final compounds are predicted to mimic the excellent electron acceptor properties of fullerene derivatives and they can be used as building blocks to form 3D semiconducting materials.
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