Na2FeO4同步氧化处理EDTA-CU废水的缩回实验研究

Jiang Dayong, Wang Xuanjun, L. Shuguang, Wang Wenguo
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引用次数: 0

摘要

由于EDTA-Cu废水中的Cu2+浓度过高,难以用一般方法去除,且状态复杂,处理是环境工程中的难点,我们尝试对高铁氧体盐EDTA-Cu废水进行同步氧化处理,取得了较好的效果。现场制备Na2FeO4作为氧化剂,既解决了成本高的问题,又简化了处理过程。以Cu2+的去除率为指标,考察了ph、投加量和反应时间三个重要因素的影响,并通过正交试验得出了相应的最佳工艺参数。结果表明,在pH=14、反应时间= 30min、投加量= 300mg/L的实验条件下,处理后的废水中Cu2+的浓度小于0.49mg/L, Cu2+的去除率可达99.1%,达到国家一级排放标准。
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Notice of RetractionExperiment Study on the Oxidation Treatment of EDTA-CU Wastewater by Na2FeO4 Synchronous
As the Cu2+ in EDTA-Cu wastewater has too high concentration to remove with general method and is in a complex state, and its handling is the difficult part in environmental engineering, we try to use synchronous Oxidation Treatment in EDTA-Cu wastewater with high ferrite salt and have achieved good results. Preparation of Na2FeO4 as an oxidant on the spot can not only solve the problem of high cost, but simplify the process of disposal. Measured by the removal rates of Cu2+ as criteria, the effect of three important factors are studied, including ph, dosage and reaction time, then corresponding optimal parameters can be acquired by the orthogonal test. The results show that the removal rate of Cu2+ can be up to 99.1% in such experimental conditions that pH=14, reaction time = 30min and dosage = 300mg/L, and the concentration of Cu2+ is less than 0.49mg/L in the treated wastewater, which also meets the national discharge standards of class I.
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