提高碱性电解电极的性能

Morten Linding Frederiksen, Marcus Viktor Kragh-Schwarz, A. Bentien, L. P. Nielsen
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引用次数: 2

摘要

多年的研究、数十年的经验和一系列的新想法促使挪威公司HydrogenPro投资成立了丹麦电镀公司Advanced Surface plating (ASP)。ASP专注于以电镀为基础的碱性电解用高性能泡沫镍电极的开发和生产。该电镀生产线于2021年第一季度至第二季度进行设计,于2021年夏季在ASP位于奥胡斯的厂房安装,同年8月投入使用,并于第四季度开始试产。目前,工业规模的电镀生产线在单个电镀1 × 1 m电极的基础上,年产能约为16000 m电极。HydrogenPro的模块化5.5 MW碱性电解槽单元基于内径188厘米的圆形电极,每个单元包含424个双极电镀和426个阳极和426个阴极。每台整机总重量大于80吨(空液运输重量)。下图1显示了位于挪威Porsgrunn的HydrogenPro测试设施中正在调试的标准化5.5 MW机组。图2显示了配备内部废水处理的ASP电镀生产线,使ASP可以回收冲洗水,从而最大限度地减少整体用水量。ASP的厂房允许生产能力增加四倍,相当于64,000 m电极的年生产能力,相当于近500 MW / pa的碱性电解能力。除了全自动电镀生产线外,ASP还建立了一个具有所有必要基础设施的研究平台,以支持进一步开发新型和优质的氢气和氧气生成电极。这包括一个化学实验室与研发电镀设施(目标电极面积为10 ×图1)。氢pro的模块化5.5兆瓦机组于2022年第四季度至2023年第一季度在挪威Porsgrunn的氢pro测试设施中投入使用(图片由氢pro提供)。
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Improved performance of electrodes for alkaline electrolysis
Years of research, decades of experience, and an array of new ideas have led the Norwegian company, HydrogenPro, to invest in the establishment of the Danish plating company Advanced Surface Plating (ASP). ASP is focusing on the development and production of high-performing nickel foam electrodes for alkaline electrolysis based on electroplating. The plating line was designed in Q1–Q2, 2021, installed in ASP’s premises in Aarhus during the summer of 2021, commissioned in August the same year, and pilot production was initiated in Q4. Currently, the industrial-scale plating line has an annual capacity of approximately 16.000 m electrodes based on individual plating of 1 × 1 m electrodes. HydrogenPro’s modularised 5.5 MW alkaline electrolyser units are based on an inside diameter of 188 cm circular electrodes with each unit containing 424 bipolar plated and 426 anodes and 426 cathodes. The total weight of each unit is more than 80 tons (transport weight empty of liquid). Figure 1, below, shows HydrogenPro’s standardised 5.5 MW unit under commissioning at HydrogenPro’s test facilities in Porsgrunn, Norway. Figure 2 shows the ASP plating line equipped with in-house waste-water treatment, allowing ASP to recycle rinsing water, thus minimising the overall water consumption. The premises at ASP allow for a potential increase of the production capacity by a factor of four, corresponding to a total annual production capacity of 64.000 m electrodes equivalent to an alkaline electrolysis capacity of nearly 500 MW pa. Besides the fully automatic plating line, ASP has established a research platform with all necessary infrastructure for supporting further development of new and superior electrodes for hydrogen and oxygen formation. This includes a chemistry laboratory with R&D-plating facilities (targeting an electrode area of 10 × Figure 1. HydrogenPro’s modularised 5.5 MW unit commissioned in Q4 2022 – Q1 2023 at HydrogenPro’s test facilities in Porsgrunn, Norway (Image courtesy HydrogenPro).
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