M. Manjunatha, N. Banu, Mohamed Ziaulla, F. Rehman, Puttaraje Gowda
{"title":"双-[1-(对甲氧基苯基)-2-(对甲氧基苯基)- 1h -苯并咪唑]四溴咪甲酸酯(II)的合成及晶体结构研究","authors":"M. Manjunatha, N. Banu, Mohamed Ziaulla, F. Rehman, Puttaraje Gowda","doi":"10.7598/cst2019.1580","DOIUrl":null,"url":null,"abstract":"The complex Cd(L)2Br4, contains a dibromocadmate(II) coordinated to two benzimidazole moiety. In the crystal structure the molecules are further interconnected with weak intermolecular CH⋅⋅⋅O hydrogen bonds generating a three-dimensional network. Further the supramolecular assembly is stabilized by Intermolecular C-H⋅⋅⋅π and π⋅⋅⋅π interactions provide additional stability to the structure. Additionally the metal ion Cd(II) exhibits a distorted tetrahedral coordination of the bromine atoms.","PeriodicalId":10087,"journal":{"name":"Chemical science transactions","volume":"25 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Crystal Structure Studies of Bis- [1-(p-methoxybenzyl)-2-(p-methoxyphenyl)-1H-benzimidazole]tetrabromidocadmate(II)\",\"authors\":\"M. Manjunatha, N. Banu, Mohamed Ziaulla, F. Rehman, Puttaraje Gowda\",\"doi\":\"10.7598/cst2019.1580\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The complex Cd(L)2Br4, contains a dibromocadmate(II) coordinated to two benzimidazole moiety. In the crystal structure the molecules are further interconnected with weak intermolecular CH⋅⋅⋅O hydrogen bonds generating a three-dimensional network. Further the supramolecular assembly is stabilized by Intermolecular C-H⋅⋅⋅π and π⋅⋅⋅π interactions provide additional stability to the structure. Additionally the metal ion Cd(II) exhibits a distorted tetrahedral coordination of the bromine atoms.\",\"PeriodicalId\":10087,\"journal\":{\"name\":\"Chemical science transactions\",\"volume\":\"25 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-04-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical science transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.7598/cst2019.1580\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical science transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.7598/cst2019.1580","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Crystal Structure Studies of Bis- [1-(p-methoxybenzyl)-2-(p-methoxyphenyl)-1H-benzimidazole]tetrabromidocadmate(II)
The complex Cd(L)2Br4, contains a dibromocadmate(II) coordinated to two benzimidazole moiety. In the crystal structure the molecules are further interconnected with weak intermolecular CH⋅⋅⋅O hydrogen bonds generating a three-dimensional network. Further the supramolecular assembly is stabilized by Intermolecular C-H⋅⋅⋅π and π⋅⋅⋅π interactions provide additional stability to the structure. Additionally the metal ion Cd(II) exhibits a distorted tetrahedral coordination of the bromine atoms.
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