三(二溴甲基甲烷)铕(III)对2,2,3,4,4-五甲基磷酸基氧化物的构型赋值

J. Corfield, S. Trippett
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引用次数: 11

摘要

2,2,3,4,4-五甲基磷酸基氧化物的顺式和反式异构体在三(二二甲基甲烷)铕(III), Eu(DPM)3存在下,可以通过它们各自的3个质子的顺磁位移来区分它们。
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Assignment of configuration to 2,2,3,4,4-pentamethylphosphetan oxides using tris(dipivalomethanato)europium(III)
cis- and trans-isomers of 2,2,3,4,4-pentamethyl-phosphetan oxides can be distinguished by the paramagnetic shifts of the respective 3-protons in their n.m.r. spectra in the presence of tris(dipivalomethanato) europium(III), Eu(DPM)3.
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