用物理化学方法探讨尿嘧啶与没食子酸水溶液中存在的各种相互作用

Samapika Ray, H. Rahaman, Kanak Roy, M. Roy
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引用次数: 0

摘要

通过物理化学研究,研究了尿嘧啶与没食子酸在水环境中的溶质-溶质相互作用。本文在T= 298.15 K, 303.15 K和308.15 K,压力为1.013 bar时,对没食子酸二元水相混合物w1= 0.001, 0.002和0.003质量分数下的尿尿素进行了密度(ρ)和粘度(η)测量。利用扩展的Masson方程和Jones-Dole方程推导出了上述物理化学方法的一些重要参数,即极限表观摩尔体积(φV0)和粘度b系数。在T=298.15 K时,对同一体系进行了折射率(nD)测定。洛伦兹-洛伦兹方程被用来计算摩尔折射率(RM)和极限摩尔折射率(RM0)。核磁共振研究用于测量溶质-溶质相互作用的可能选择位点。
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Assorted Interactions Prevalent in Uracil and Aqueous Gallic Acid Solution Explored by Physicochemical Contrivance
The solute-cosolute interaction of uracil by gallic acid has been studied through physicochemical investigation in aqueous environment. Here, we have carried out the density (ρ) and viscosity (η) measurements of uracil in w1= 0.001, 0.002 and 0.003 mass fraction of aqueous gallic acid binary mixtures at T= 298.15 K, 303.15 K and 308.15 K at pressure 1.013 bar. Some important parameters have been derived from the above physicochemical method, namely, limiting apparent molar volume (φV0) and viscosity B-coefficients using extended Masson equation and Jones-Dole equation respectively. The refractive index (nD) has been done on the same system at T=298.15 K. Lorentz-Lorenz equation has used to evaluate molar refractive index (RM) and limiting molar index (RM0). The NMR study used to measure the plausible selective site of solute-cosolute interaction.
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