钛酸锶/聚碳酸酯纳米复合储能电极的介电响应

A. Yadav, D. Yadav, S. K. Jain, B. Tripathi, R. Katiyar
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引用次数: 0

摘要

在本研究中,我们报道了用溶液浇铸法合成厚度为100 μm的钛酸锶(SrTiO3表示为ST,以1-5 mwt%作为填料)/聚碳酸酯(PC)纳米复合材料的介电响应。聚碳酸酯作为被动基体元件,陶瓷钛酸锶(SrTiO3)分散在聚碳酸酯中,以提高有效介电响应。利用x射线衍射(XRD)、傅里叶变换红外(FT-IR)和扫描电子显微镜(SEM)分别对制备的纳米复合材料的结构、键合和形貌进行了表征。本文着重介绍了用阻抗分析仪检测复合材料的介电响应。随着聚碳酸酯基体中SrTiO3浓度的增加,介电常数也随之增加。在1khz时,ST5%PC95%复合材料的介电常数高达6.61。这些高介电常数的复合材料可作为储能装置的高性能电极材料。
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Dielectric Response of Strontium Titanate (SrTiO3)/Polycarbonate Nanocomposite Electrodes for Energy Storage
In the present study we are reporting dielectric response of strontium titanate (SrTiO3 represented as ST used as filler in 1–5 mwt%)/polycarbonate (PC) nanocomposites of thickness 100 μm synthesized by solution cast method. Polycarbonate serving as passive matrix element and ceramic strontium titanate (SrTiO3) dispersed into polycarbonate to improve effective dielectric response. X-ray diffraction (XRD), Fourier transform infrared (FT-IR) and Scanning electron microscopy (SEM) have been used to investigate structural, bonding and morphological properties of fabricated nanocomposites respectively. Particular attention has been given on the examination of dielectric response for composites using Impedance analyzer. Dielectric constant has been found to be increased with increasing concentration of SrTiO3 inside the polycarbonate matrix. The observed dielectric constant reaches upto 6.61 for ST5%PC95% composite at 1 KHz. These composites of high dielectric constant can be used as high performance electrode materials for electrical energy storage devices.
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