铁(III)、镍(II)和钴(II)的可聚合β-酮酯配合物催化醛、酮、硫化物、醇和烷烃的有氧氧化

Q4 Chemical Engineering 分子催化 Pub Date : 1994-11-13 DOI:10.1016/0304-5102(94)87027-6
R. Giannandrea, P. Mastrorilli, C.F. Nobile, G.P. Suranna
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引用次数: 43

摘要

醛、酮、硫化物、醇和烷烃的氧化是通过在室温和常压(Mukaiyama条件)下使用铁(III)、镍(II)或钴(II)的可溶性β-酮酯配合物在支链醛和分子氧(或空气)的存在下实现的。
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Aerobic oxidation of aldehydes, ketones, sulfides, alcohols and alkanes catalysed by polymerizable, β-ketoesterate complexes of iron(III), nickel(II) and cobalt(II)

The oxidation of aldehydes, ketones, sulfides, alcohols and alkanes is achieved by using a soluble β-ketoesterate complex of iron (III), nickel (II) or cobalt (II) in the presence of a branched aldehyde and molecular oxygen (or air) at room temperature and atmospheric pressure (Mukaiyama's conditions).

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来源期刊
分子催化
分子催化 Chemical Engineering-Catalysis
CiteScore
1.50
自引率
0.00%
发文量
2959
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Author index Subject index Hydrolysis of sucrose by dealuminated Y-zeolites Synthesis and application of organophilic polystyrene-montmorillonite supported onium salts in organic reactions Effect of the reduction temperature on the selectivity of the high temperature reaction of acetone and hydrogen over alumina and titania supported nickel and cobalt catalysts
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