{"title":"活性硅。化学吸附硅烷的热解","authors":"M. Low, M. Shimizu, J. Mcmanus","doi":"10.1039/C2971000579B","DOIUrl":null,"url":null,"abstract":"When silica bearing creatain chemisorbed silanes is heated to a high temperatrure in vacuo, the chemisorbed layer is disrupted and the surface of the silica is modified; surface =SiH2 groups are formed and the silica surface becomes unusually reactive.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"50 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Reactive silica. Pyrolysis of chemisorbed silanes\",\"authors\":\"M. Low, M. Shimizu, J. Mcmanus\",\"doi\":\"10.1039/C2971000579B\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"When silica bearing creatain chemisorbed silanes is heated to a high temperatrure in vacuo, the chemisorbed layer is disrupted and the surface of the silica is modified; surface =SiH2 groups are formed and the silica surface becomes unusually reactive.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"50 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C2971000579B\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C2971000579B","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
When silica bearing creatain chemisorbed silanes is heated to a high temperatrure in vacuo, the chemisorbed layer is disrupted and the surface of the silica is modified; surface =SiH2 groups are formed and the silica surface becomes unusually reactive.