聚合物交联、熔融、软化和渗透过程中的自发电流(SEC)和电位(SEP)

P. Elsner, P. Eyerer
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引用次数: 0

摘要

当过渡锋或相锋在介电材料内移动时,可以在没有施加外部电压(零偏置)的情况下观察到自发电位(SEP)或自发电流(SEC)。我们在聚氨酯、聚硅氧烷、未增强和玻璃纤维增强环氧树脂、不饱和聚酯树脂的交联过程中发现了这种效应,在热塑性塑料的软化、熔化和结晶过程中也发现了这种效应,在聚酰胺和聚氨酯薄膜的水渗透过程中也发现了这种效应。
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Spontaneous electrical current (SEC) and potentials (SEP) curing crosslinking melting, softening and permeation processes in polymers
When a transition front or a phase front moves within a dielectric material, a spontaneous electrical potential(SEP) or a spontaneous electrical current (SEC) can be observed without applied external voltage (zero bias). We found this effect during crosslinking of polyurethane, polysiloxane, unreinforced and glass fiber reinforced epoxy resins, and unsaturated polyester resins and also during softening, melting and crystallization of thermoplastics and during permeation of water through polyamide and polyurethane films.
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