TiO2-N-GO纳米复合材料光催化含硫废水制氢研究

D. Sponza
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引用次数: 0

摘要

本研究通过在氧化石墨烯上掺杂含氮的TiO2纳米颗粒,在实验室条件下制备TiO2- n -GO纳米复合材料,在紫外光下处理含高浓度H2S的化工废水。研究了TiO2-N-GO纳米复合材料在1%-1% -3%、3%- 1%-1%和1%- /15%-1 - %3比例下的最大产氢率。采用XRD、UV-DRS、Raman、XPS、FESEM和TEM等手段对纳米复合材料的结构、光学和形貌进行了研究。TiO2-N-GO纳米复合材料中GO含量为2%,在60 min紫外光照射下光催化产氢量增强3450 μmol h−1,其光催化活性的提高是由于高N掺杂导致纳米复合材料表面高多孔性。
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H2 Production From Wastewaters Containing Sulphur via Photocatalysis Using TiO2-N-GO Nanocomposite
In this study, nitrogen containing TiO2 nanoparticles were doped on GO and TiO2-N-GO nanocomposite was produced under laboratory conditions to treat the chemical industry wastewater containing high H2S under UV light. 1%- 1%-3%, 3%- 1%-1% and 1%- /15%-1%3 ratios for TiO2-N-GO nanocomposite composition was researched for maximal hydrogen production. The structural, optical and morphological aspects of nanocomposites were studied using XRD, UV-DRS, Raman, XPS, FESEM, and TEM. The TiO2-N-GO nanocomposite with 2% GO, exhibited enhanced photocatalytic H2 production 3450 μmol h−1 under 60 min UV light irradiation The increase of photocatalytic activity was the high N doping resulting in high porous surface in the nanocomposite.
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