功能化单壁碳纳米管/壳聚糖/聚苯胺纳米复合材料的合成与表征

IF 1.2 Q4 NANOSCIENCE & NANOTECHNOLOGY international journal of nano dimension Pub Date : 2016-01-01 DOI:10.7508/IJND.2016.01.003
Z. Abdi, S. Sedaghat
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引用次数: 3

摘要

摘要:本文研究了聚苯胺/壳聚糖/功能化单壁碳纳米管纳米复合材料的合成。为此,将单壁碳纳米管与亚硫酰氯反应,使羟基变为酰氯,从而提高反应能力。第二步,苯胺单体与壳聚糖在氯化铁(III)存在下聚合,合成chitaline共聚物。将合成的chitaline与功能化的单壁碳纳米管反应,制备chitaline-单壁碳纳米管纳米复合材料。利用傅里叶红外光谱(FT-IR)、扫描电镜(SEM)和热重分析(TGA)对合成的纳米复合材料进行了结构和形貌表征。结果表明,在纳米尺度上形成的复合材料可作为提高多孔表面吸附性能的良好碳材料,是去除水中有机和无机废物的良好候选材料,如纳米生物过滤器。
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Synthesis and characterization of functionalized single - walled carbon nanotube/ chitosan/polyaniline nanocomposite
ABS TRACT: In this work the synthesis of polyaniline/chitosan/functionalized single- walled carbon nanotube nanocomposite is carried out. For this purpose, single -walled carbon nanotubes were reacted with thionyl chloride to change the hydroxyl to acyl chloride groups for improving the react ability. In other step, aniline monomers and chitosan were polymerized in the presence of Iron (III) Chloride to synthesize the chitaline copolymer. The synthesized chitaline then reacted with functionalized single- walled carbon nanotube to prepare chitaline-single walled carbon nanotube nanocomposite. The synthesized nanocomposite was also characterized to evaluate the structure and morphology by Fourier infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and thermo gravimetric analysis (TGA). The results showed that the formation of the composite in nano scale can be good carbon materials with high adsorption capacity in porous surfaces for improving the properties as a good candidate such as nano bio filter for removing the organic and inorganic wastes from water.
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来源期刊
international journal of nano dimension
international journal of nano dimension NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
2.80
自引率
20.00%
发文量
0
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