沥青粘结剂性能与原料组成及氧化条件的关系

A.M. Isakov, V. Kapustin, D. Nebratenko, S. Stupak
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引用次数: 1

摘要

沥青是一种组成复杂而特殊的有机材料,其物理、机械、化学、粘接等性能在很大程度上取决于其基团组成及其所含烃类组分的比例。这些性能反过来又与原料的组成直接相关,这是由油肩带的加工水平(深度)和不同水平的精炼产品的氧化和复合方法决定的。这项工作评估了沥青原料的初始基团组成及其在不同条件下氧化过程中的变化。研究表明,氧化过程以热氧化破坏过程为主,饱和烃馏分分解为芳烃馏分、树脂馏分和部分芳烃馏分分解为沥青质,容易发生团聚。该研究的结果扩大了对通过改变供氧化的油链的组成来调节商业沥青和基于它们的聚合物沥青粘合剂性能的潜力的认识。利用所得数据对Salavat“BITUM”有限责任公司的生产工艺进行了优化,以实现商品沥青和PMB的大规模生产。生产的粘合剂于2018-2019年在伏尔加河联邦区用于生产沥青混凝土和聚合物沥青混凝土混合物以及基于它们的涂料装置。
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Dependence of properties of bituminous binders on composition of raw materials and conditions of oxidation
Bitumen is a complex and specific in its composition organic materials, the physicomechanical, chemical, adhesive and other properties of which significantly depend on their group composition and the ratio of hydrocarbon fractions included in them. These properties, in turn, are directly related to the composition of the feedstock, which is determined by the level (depth) of processing of oil shoulder straps and the methods of oxidation and compounding of refined products of different levels. This work evaluates the group composition of the initial bituminous raw material and its changes during oxidation under various conditions. The study showed that the oxidation process is dominated by the processes of thermal oxidative destruction, leading to the decomposition of fractions of saturated hydrocarbons into aromatic, resinous and partially aromatic fractions into asphaltenes prone to agglomeration. The results of the study expand knowledge about the development of the potential for regulating the properties of commercial bitumen and polymer-bitumen binders based on them by varying the composition of oil strands supplied for oxidation. The data obtained were used to optimize the production processes of LLC "BITUM", Salavat, for the purpose of large-scale production of commercial bitumen and PMB. The binders produced were used in 2018-2019 for the production of asphalt concrete and polymer-asphalt concrete mixtures and the device of coatings based on them in the Volga Federal District.
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