181Ta自旋弛豫测量氢在非晶Zr2NiH2.5中的扩散

A. Chikdene, A. Baudry, P. Boyer
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引用次数: 4

摘要

采用微扰角相关(PAC)技术,用181Ta自旋弛豫测量了氢在非晶Zr2NiH2.5中的扩散运动。自旋弛豫常数的温度依赖性对应的活化能明显低于结晶氢化物Zr2NiH3,但并不表明氢的扩散存在大的跳速分布。
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Hydrogen diffusion in amorphous Zr2NiH2.5 by 181Ta spin relaxation measurements
The diffusive motions of hydrogen in amorphous Zr2NiH2.5 were observed by 181Ta spin relaxation measurements with the perturbed angular correlation (PAC) technique. The temperature dependence of the spin relaxation constant corresponds to an activation energy significantly lower than in the crystallised hydride Zr2NiH3, but does not indicate the existence of a large distribution of hopping rates for the diffusion of hydrogen.
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