电荷转移引起的热刺激电流

K. Shindo
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引用次数: 0

摘要

用空间电荷转移解释了聚对苯二甲酸乙二酯驻极体热激去极化电流(TSDC)热图中高温峰的存在。从陷阱中释放出的电子和空穴使空间电荷处于传输态,这种传输态被认为具有跳变性质。热激发迁移率的概念应用于这一过程。用联立微分方程描述了阱态和输运态之间的跃迁和输运态中的电荷转移。我们对这些方程进行数值求解,并调整参数使计算出的峰值尽可能地再现观测到的峰值。
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Thermally stimulated current by charge transfer
A peak at high temperature in a thermogram of thermally stimulated depolarization current (TSDC) of an electret of polyethylene-terephthalate is explained with space charge transfer. Electron and/or holes released from traps make space charge in transport state which is assumed to be of a hopping nature. A concept of thermally stimulated mobility is applied to this process. Transition between trap and transport state, and charge transfer in the latter states are described with simultaneous differential equations. We solve these equations numerically and adjust parameters to make a calculated peak reproduce an observed one as well as possible.
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