碳水化合物包覆的硫化镉纳米颗粒的结构、光学和抗菌性能

Subhav Adhikari, K. Parajuli, Guna B. Karki, Shankar P. Khatiwada, R. Adhikari
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引用次数: 0

摘要

以甘薯淀粉和葡萄糖为封盖剂,采用化学沉淀法制备了硫化镉颗粒(cdsnp)。采用紫外可见光谱(UV-Vis)、傅里叶变换红外光谱(FTIR)和x射线衍射(XRD)技术对制备的cdsnp进行了分析。与块体CdS (512 nm)相比,紫外可见光谱吸收峰在较低波长区域,表明CdS颗粒的形成在纳米尺度范围内。FTIR光谱显示CdSNPs的特征吸收峰与淀粉和葡萄糖中存在的官能团一致,表明CdSNPs可能与封盖剂相互作用。XRD显示了CdSNPs的平均晶粒尺寸和形状等晶体学信息。利用Scherrer方程,测定了淀粉盖顶CdSNPs和葡萄糖盖顶CdSNPs (CdS-St和cds - gl)的平均晶粒尺寸分别为11.48 nm和16.03 nm。所制备的CdSNPs对多种病原菌和真菌具有高效的抗菌和抗真菌活性。因此,本研究采用了新的CdSNPs合成途径,并进行了抗菌活性研究
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Structural, Optical and Antimicrobial Properties of Carbohydrate-Capped Cadmium Sulfide Nanoparticles
Cadmium sulfidenanoparticles (CdSNPs) were prepared through the chemical precipitation process where sweet potato starch and glucose-functioned as capping agents. Ultraviolet-Visible (UV-Vis) spectroscopy, Fourier Transform Infrared (FTIR) spectroscopy and X-ray diffraction (XRD) techniques were applied for the analysis of prepared CdSNPs. The absorption peaks in the UV-Vis spectroscopy towards the lower wavelength region compared to the bulk CdS (512 nm) indicated the formation of CdS particles in the nanometer scale range. FTIR spectroscopy showed the characteristic absorption peaks of the CdSNPs along with the functional groups present in starch and glucose, suggesting the possible interaction between CdSNPs and capping agents. The XRD revealed crystallographic information such as the average crystallite size and shape of CdSNPs. Using the Scherrer equation, the average crystallite size of CdSNPs was determined to be 11.48 nm and 16.03 nm for starch-capped and glucose-capped CdSNPs (CdS-St andCdS-Gl)respectively. Antibacterial and antifungal activities of the prepared CdSNPs were found to be highly efficient for various pathogenic bacteria and fungi. Hence in the present study, the new synthetic route of CdSNPs was applied, and antimicrobial activities were performed
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