{"title":"2、4 Dinitrobenzenesulfenyl氯","authors":"Judi A. McKinney","doi":"10.1002/047084289X.RD398","DOIUrl":null,"url":null,"abstract":"[528-76-7] C6H3ClN2O4S (MW 234.63) \n \n \n \n \n \nInChI = 1S/C6H3ClN2O4S/c7-14-6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H \n \n \n \nInChIKey = GPXDNWQSQHFKRB-UHFFFAOYSA-N \n \n \n \n(sulfenylation agent used in electrophilic additions,1, 2 diene synthesis,12 protection of nucleosides,13 and preparation of propargyl alcohol synthons for use in cycloaddition chemistry15) \n \n \n \nAlternate Name: 2,4-dinitrophenylsulfenyl chloride. \n \n \n \nPhysical Data: mp 94–97 °C. \n \n \n \nSolubility: sol most common organic solvents. \n \n \n \nForm Supplied in: commercially available as a solid (96% pure). \n \n \n \nHandling, Storage, and Precautions: corrosive; lachrymator. This reagent should be handled in a fume hood.","PeriodicalId":11669,"journal":{"name":"Encyclopedia of Reagents for Organic Synthesis","volume":"65 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2001-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"2,4‐Dinitrobenzenesulfenyl Chloride\",\"authors\":\"Judi A. McKinney\",\"doi\":\"10.1002/047084289X.RD398\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"[528-76-7] C6H3ClN2O4S (MW 234.63) \\n \\n \\n \\n \\n \\nInChI = 1S/C6H3ClN2O4S/c7-14-6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H \\n \\n \\n \\nInChIKey = GPXDNWQSQHFKRB-UHFFFAOYSA-N \\n \\n \\n \\n(sulfenylation agent used in electrophilic additions,1, 2 diene synthesis,12 protection of nucleosides,13 and preparation of propargyl alcohol synthons for use in cycloaddition chemistry15) \\n \\n \\n \\nAlternate Name: 2,4-dinitrophenylsulfenyl chloride. \\n \\n \\n \\nPhysical Data: mp 94–97 °C. \\n \\n \\n \\nSolubility: sol most common organic solvents. \\n \\n \\n \\nForm Supplied in: commercially available as a solid (96% pure). \\n \\n \\n \\nHandling, Storage, and Precautions: corrosive; lachrymator. This reagent should be handled in a fume hood.\",\"PeriodicalId\":11669,\"journal\":{\"name\":\"Encyclopedia of Reagents for Organic Synthesis\",\"volume\":\"65 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-04-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Encyclopedia of Reagents for Organic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/047084289X.RD398\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Encyclopedia of Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/047084289X.RD398","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
[528-76-7] C6H3ClN2O4S (MW 234.63)
InChI = 1S/C6H3ClN2O4S/c7-14-6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H
InChIKey = GPXDNWQSQHFKRB-UHFFFAOYSA-N
(sulfenylation agent used in electrophilic additions,1, 2 diene synthesis,12 protection of nucleosides,13 and preparation of propargyl alcohol synthons for use in cycloaddition chemistry15)
Alternate Name: 2,4-dinitrophenylsulfenyl chloride.
Physical Data: mp 94–97 °C.
Solubility: sol most common organic solvents.
Form Supplied in: commercially available as a solid (96% pure).
Handling, Storage, and Precautions: corrosive; lachrymator. This reagent should be handled in a fume hood.
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