棕榈和瓜油二元共混生产生物柴油的热力学研究

Kalu Samuel Anthonio, Ibezim Ezeani Millicent Uzoamaka, Monago Kenneth Osondu, Njoku Chika Mercy
{"title":"棕榈和瓜油二元共混生产生物柴油的热力学研究","authors":"Kalu Samuel Anthonio, Ibezim Ezeani Millicent Uzoamaka, Monago Kenneth Osondu, Njoku Chika Mercy","doi":"10.9734/irjpac/2023/v24i3811","DOIUrl":null,"url":null,"abstract":"Environmental pollutions, energy problems and other uncertainties associated with the use of fossil fuel are some reasons which constitute the quest for eco-compatible fuel substitutes. Vegetable oils (VOs) are known raw materials that will remedy the situation. Palm oil (PO) and melon oil (MO) were extracted and blended in various proportions PO:MO (0:100, 10:90, 30:70, 40:60, 50:50, 60:40, 80:20, 100:0) for biodiesel (BDS) production through the process of trans esterification using a catalyst (sodium hydroxide, NaOH). Viscosities of the blends decrease as temperature increases. Experimental information was applied to Grunberg-Nissan (d-)parameter; the range of PO50: MO50 blend (-10.629 to -8.030) showed the least negative d-parameter values at all temperatures (283K to 323K) and viscosity deviations at various temperatures range between -20 to 21. Thermodynamic studies were carried out on the blends; the randomness of the system and negligible effect of inter- and intra- bonding energies of the system were defined by the increasing negative values of Gibbs free energy of mixing (ΔGM) and zero enthalpies of mixing (ΔHM = 0). Energies of the produced BDS increase as calorific values of the blends increase (36 - 49 MJ/k) with an increase in the fractions of MO, and cloud point ranges from -1 to 0oC. The biodiesel properties were found to be comparable to the American Society for Testing and Material (ASTM) standard.","PeriodicalId":14371,"journal":{"name":"International Research Journal of Pure and Applied Chemistry","volume":"59 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermodynamic Studies on BInary Blends of Palm and Melon Oils in Production of Biodiesel\",\"authors\":\"Kalu Samuel Anthonio, Ibezim Ezeani Millicent Uzoamaka, Monago Kenneth Osondu, Njoku Chika Mercy\",\"doi\":\"10.9734/irjpac/2023/v24i3811\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Environmental pollutions, energy problems and other uncertainties associated with the use of fossil fuel are some reasons which constitute the quest for eco-compatible fuel substitutes. Vegetable oils (VOs) are known raw materials that will remedy the situation. Palm oil (PO) and melon oil (MO) were extracted and blended in various proportions PO:MO (0:100, 10:90, 30:70, 40:60, 50:50, 60:40, 80:20, 100:0) for biodiesel (BDS) production through the process of trans esterification using a catalyst (sodium hydroxide, NaOH). Viscosities of the blends decrease as temperature increases. Experimental information was applied to Grunberg-Nissan (d-)parameter; the range of PO50: MO50 blend (-10.629 to -8.030) showed the least negative d-parameter values at all temperatures (283K to 323K) and viscosity deviations at various temperatures range between -20 to 21. Thermodynamic studies were carried out on the blends; the randomness of the system and negligible effect of inter- and intra- bonding energies of the system were defined by the increasing negative values of Gibbs free energy of mixing (ΔGM) and zero enthalpies of mixing (ΔHM = 0). Energies of the produced BDS increase as calorific values of the blends increase (36 - 49 MJ/k) with an increase in the fractions of MO, and cloud point ranges from -1 to 0oC. The biodiesel properties were found to be comparable to the American Society for Testing and Material (ASTM) standard.\",\"PeriodicalId\":14371,\"journal\":{\"name\":\"International Research Journal of Pure and Applied Chemistry\",\"volume\":\"59 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Research Journal of Pure and Applied Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.9734/irjpac/2023/v24i3811\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Research Journal of Pure and Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.9734/irjpac/2023/v24i3811","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

与使用矿物燃料有关的环境污染、能源问题和其他不确定因素是寻求生态相容的燃料替代品的一些原因。植物油(VOs)是可以补救这种情况的已知原料。以棕榈油(PO)和瓜油(MO)为原料,在氢氧化钠(NaOH)催化下,以PO:MO(0:100、10:90、30:70、40:60、50:50、60:40、80:20、100:0)的不同比例进行反式酯化反应,制备生物柴油(BDS)。共混物的粘度随着温度的升高而降低。将实验信息应用于Grunberg-Nissan (d-)参数;PO50: MO50共混物(-10.629 ~ -8.030)在283K ~ 323K温度范围内的负d参数值最小,粘度偏差在-20 ~ 21温度范围内。对共混物进行了热力学研究;混合吉布斯自由能的负值(ΔGM)和混合零焓值(ΔHM = 0)的增大,表明体系的随机性和键间能和键内能的影响可以忽略不计。随着MO组分的增加,共混物的热值(36 ~ 49 MJ/k)的增加,生成的BDS的能量也随之增加,云点范围从-1℃到0℃。生物柴油的性能可与美国材料试验协会(ASTM)的标准相媲美。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Thermodynamic Studies on BInary Blends of Palm and Melon Oils in Production of Biodiesel
Environmental pollutions, energy problems and other uncertainties associated with the use of fossil fuel are some reasons which constitute the quest for eco-compatible fuel substitutes. Vegetable oils (VOs) are known raw materials that will remedy the situation. Palm oil (PO) and melon oil (MO) were extracted and blended in various proportions PO:MO (0:100, 10:90, 30:70, 40:60, 50:50, 60:40, 80:20, 100:0) for biodiesel (BDS) production through the process of trans esterification using a catalyst (sodium hydroxide, NaOH). Viscosities of the blends decrease as temperature increases. Experimental information was applied to Grunberg-Nissan (d-)parameter; the range of PO50: MO50 blend (-10.629 to -8.030) showed the least negative d-parameter values at all temperatures (283K to 323K) and viscosity deviations at various temperatures range between -20 to 21. Thermodynamic studies were carried out on the blends; the randomness of the system and negligible effect of inter- and intra- bonding energies of the system were defined by the increasing negative values of Gibbs free energy of mixing (ΔGM) and zero enthalpies of mixing (ΔHM = 0). Energies of the produced BDS increase as calorific values of the blends increase (36 - 49 MJ/k) with an increase in the fractions of MO, and cloud point ranges from -1 to 0oC. The biodiesel properties were found to be comparable to the American Society for Testing and Material (ASTM) standard.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Kinetics and Equilibrium Studies of the Detoxification of Aqueous Solutions of Phenolic Derivatives using Activated Carbon Anti-Diabetic Activities of the Extracts from Euphorbia hirta L. (Euphorbiaceae) Specie found in Burkina Faso Using α-Glucosidase Inhibitor Syntheses and X-ray Structure of N-(Benzothiazol-2-yl)-3-chlorobenzamide Copper Adsorption by a Clay from Central Ivory Coast: Analysis by Differential Pulse Anodic Stripping Voltammetry Isolation and Characterization of Glucocorticoid Steriod from the Leaf of Rauvolfia vomitoria
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1