纳米氧化锆的加入对热固化丙烯酸树脂抗弯强度和孔隙率的影响

Ranj A. Omer, Fahd S. Ikram
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摘要

热固化义齿基托是目前制作活动义齿最常用的材料。然而,由于假体的机械性能较差,导致在牙科实践中经常进行修复,因此制造令人满意的假体仍然存在困难。本研究旨在探讨氧化锆纳米颗粒(ZrO2NPs)对义齿基托抗弯强度和孔隙度的影响及其相关性。用x射线衍射(XRD)检测了NPs的纯度。将NPs以1%、3%和5%的重量分散到甲基丙烯酸甲酯单体上。此外,用扫描电子显微镜(SEM)观察了丙烯酸酯内部颗粒的团聚情况。结果表明,不同浓度ZrO2NPs的抗弯强度差异显著(p<0.05)。分析表明,1%和3%的ZrO2NPs分别减少了17%和11%,而5%的ZrO2NPs与对照相比减少了32%。在孔隙度方面,不同浓度的结果与对照组相比无统计学差异。抗折强度与孔隙率呈显著负相关(-0.83)。但结果无统计学意义(p=0.369)。在本研究的限制范围内,可以得出结论,添加ZrO2会导致所有添加浓度的抗弯强度降低。而对丙烯酸树脂的孔隙率影响不显著。合适的添加剂来提高PMMA的性能。
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Effect of Addition Of Zirconium Oxide Nanoparticles on Flexural Strength and Porosity of Heat Cure Acrylic Resin
Heat cure denture base is the most commonly used material for fabrication of removable prosthesis to the present day. However difficulties persist in fabrication of satisfactory prosthesis due to poor mechanical properties which have resulted in frequent repairs in dental practice. The present study is aimed to investigate the effect of Zirconium oxide nanoparticles (ZrO2NPs) on flexural strength and porosity of denture base and its correlation. X-ray diffraction (XRD) was used to check the purity of NPs. NPs was dispersed at 1%, 3% and 5% by weight to the monomer of methyl methacrylate with aid of probe sonicator. In addition, Scanning Electron Microscope (SEM) was used to observe agglomeration of particles within the acrylic. The results revealed significant flexural strength difference (p<0.05) between each concentration of ZrO2NPs. The analysis showed 17% and 11% reduction for 1% and 3% ZrO2NPs respectively while 5% caused a drastic reduction by 32% in reference to control. In regards to porosity, the results present no statistically significant difference among the concentrations in contrast to control. Pearson correlation showed strong and a negative relation (-0.83) between flexural strength and porosity. However, the results was not statistically significant (p=0.369). Within the limitations of this study, it can be concluded that the addition of ZrO2 caused reduction in flexural strength for all concentrations added. While it caused non-significant effect on porosity of acrylic. suitable additive to enhance the properties of PMMA.
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