高分子复合材料中基于胶原蛋白的生物添加剂

A. Baldanov, L. Bokhoeva, D. Shalbuev, T. Tumurova
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引用次数: 0

摘要

:介绍。以环氧树脂为基础的高分子复合材料(PCM)在建筑工业中得到了广泛的应用。它们适用于桥梁跨径、道路板、人行道板、低荷载结构的施工,以及混凝土结构的加固、护层、金属和混凝土结构的加固。采用各种微、纳米级填料来改善PCM的性能。填料与聚合物基体之间的界面相互作用是决定复合材料强度的重要因素。方法和材料。研究了从皮革工业固体有机废弃物中提取的胶原基生物添加剂增强聚合物基复合材料的性能。我们开发了一种全新的方法,以相对较低的价格获得生物活性胶原蛋白产品,专利RU No. 2272808描述。通过将干燥的胶原蛋白粉末加入到环氧粘合剂中,对PCM样品进行了拉伸研究。用JSM-6510LVJEOL扫描电镜对样品切片进行了分析,研究了填料对PCM结构的影响。结果和讨论。当PCM基质中加入1%的胶原蛋白时,化学元素的数量增加:碳(C)增加2.93%,氧(O)增加1.61%,镁(Mg)增加0.11%。基体表面起应力集中作用的微孔数量减少了4.9%,微孔尺寸也在减小。拉伸试验表明,当PCM基质中加入1%的胶原蛋白时,样品的承载力提高了15.57%。所得结果有助于扩大胶原蛋白的应用,减少皮革工业中因回收而产生的废物。结论。一种从皮革工业的固体有机废物中以相对较低的价格获得生物活性胶原蛋白产品的新方法已经被开发出来。研究表明,粉末形式的生物活性胶原蛋白产品成本低,可作为PCM的生物添加剂。
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Collagen Based Bio-Additives in Polymer Composites
: Introduction. Polymer composite materials (PCM) based on epoxy resins are widely used in the construction industry. They are applied in construction of bridge spans, roadway slabs, footwalk planks, in low-loaded structures, as well as for reinforcement of concrete structures, sheating, strengthening of metal and concrete structures. Various fillers of micro- and nanosizes are used to improve the performance properties of PCM. Interfacial interaction between the filler and the polymer matrix plays an important role in determining the strength of the created composite materials. Methods and materials. The article studies the properties of polymer matrix composites reinforced with collagen based bio-additives obtained from solid organic waste of the leather industry. We have developed a fundamentally new method for obtaining a bioactive collagen product at a relatively low price, described in patent RU No. 2272808. Tensile studies of the PCM samples were carried out by adding dry collagen powder to an epoxy binder. We analyzed the sections of samples made on a JSM-6510LVJEOL scanning electron microscope, and studied the changes in the structure of PCM with fillers. Results and discussion. When 1% collagen is added to the PCM matrix, the amount of chemical elements is increasing: carbon (C) by 2.93%, oxygen (O) by 1.61%, magnesium (Mg) by 0.11%. And the number of micropores on the surface of the matrix, which serve as a stress concentrator, is decreasing by 4.9%, and they are also diminishing in size. The tensile tests have shown that when 1% collagen is added to the PCM matrix, the bearing capacity of the samples is increasing by 15.57%. The results obtained can contribute to the expansion of collagen application, waste reduction in the leather industry due to recycling. Conclusion. A fundamentally new method has been developed for obtaining a bioactive collagen product from solid organic waste of the leather industry at a relatively low price. It has been established that a bioactive collagen product in a powder form has a low cost and can be used as a bio-additive for PCM.
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来源期刊
CiteScore
2.30
自引率
58.30%
发文量
37
审稿时长
8 weeks
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