高硫化氢气田货币化:一种新方法

A. Jariwala
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引用次数: 1

摘要

根据美国能源信息署(EIA)的数据,世界上40%的石油储量是酸性的。这给原料气中硫化氢含量远高于5 mol%的超含硫气田带来了巨大的挑战和经济负担。目前,大多数超含硫气田都采用常规处理技术,如胺溶剂法和克劳斯法制硫、硫回收装置和尾气处理装置(SRU-TGTU)。作为独立的流程,该流程的资本和运营成本非常高。此外,整体硫磺生产需要当地需求来解决整体硫磺处理成本。随着硫化氢含量高于5-36%的超酸油田越来越多,在生产如此大量硫的同时,运营商很难保持健康的生产利润。随着超含酸气的生产,它面临着许多健康安全和环境(HSE)挑战。开发了一种新的超含酸气田气体处理技术方法。该方法采用混合工艺,使用最先进的H2S去除膜,在上游进行H2S的大量分离,然后是小胺和克劳斯装置。这是理想的解决方案,独特的膜能够承受高H2S环境而不改变其性能。这些膜将分离富含H2S的流体,是回注或提高采收率(EOR)的理想选择。膜在高压产物气中保留了最多的碳氢化合物,这在气体生产中非常有价值。低压富H2S流为干水流,可直接回注。这些膜还可以捕获二氧化碳并去除H2S。将独特的膜技术与较小的胺和克劳斯工厂相结合,将降低给定项目预算的总体CAPEX和OPEX要求。膜更安全,没有任何排放问题。这将使工厂更加安全。与独立的大型硫磺工厂相比,较低的资本支出和总体较低的总拥有成本(TCO)将使运营商能够将超含硫气田货币化,并提供更好的投资回报。
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High H2S Gas Field Monetization: A Novel Approach
As per EIA, 40% of the world reserves are sour. This has imposed significant challenges and economic burden to monetize ultra-sour gas fields with H2S levels much higher than 5 mol% in the raw gas. Currently most of the ultra-sour gas fields are monetized by using conventional treating technologies like amine solvent process followed a Claus based process to produce sulfur, Sulfur recovery unit and Tail gas treatment unit, SRU-TGTU. This process is extremely capital and operating cost prohibitive as standalone processes. Also, the overall Sulfur production requires a local demand to address overall sulfur disposal cost. With growing number of fields with higher than 5-36% H2S, ultra-sour fields, it’s difficult for operators to maintain healthy production profits while producing such large quantity of sulfur. With ultra-sour gas production, it has many Health Safety and Environmental (HSE) challenges. A new gas treating technology approach is developed to address ultra-sour fields. The approach is using hybrid process by using state of the art H2S removal membranes to do bulk separation of H2S upstream followed by small amine and Claus plant. This is ideal solution where unique membranes have ability to withstand high H2S environment without altering its performance. These membranes will separate H2S enriched stream which is ideal for reinjection or potentially used for Enhanced Oil Recovery (EOR). The membranes retain maximum hydrocarbons in the high-pressure product gas which very valuable in gas production. Low pressure H2S rich stream is water dry and can be reinjected directly. These membranes will also address CO2 capture along with H2S removal. Using combination of unique membrane technology with smaller amine and Claus plant will reduce the overall CAPEX and OPEX requirement for a given project budget. Membranes are much safer and does not have any emission issues. This will allow plants to be much more HSE safe. Having lower CAPEX and overall lower total cost of ownership (TCO) will allow operators to monetize ultra-sour gas fields and provide better return on investment compared to standalone large sulfur plants.
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