聚苯乙烯在环烷烃和正烷烃中的相行为比较

J. Cowie, I. McEwen
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引用次数: 1

摘要

本文建立了聚苯乙烯在环庚烷、环辛烷和环癸烷中溶解的几种窄馏分的云点曲线,并通过临界溶解温度外推得到了相应的温度。这三种环烷烃都是聚合物的良好溶剂。用自由体积聚合物溶液理论比较了聚苯乙烯在环烷烃和正烷烃中的相行为。
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A Comparison of the Phase Behaviour of Polystyrene in Cycloalkanes and n‐Alkanes
Cloud point curves for several narrow fractions of polystyrene dissolved in cycloheptane, in cyclooctane and in cyclodecane have been established, and the critical solution temperatures extrapolated to give the respective temperatures. All three cycloalkanes are good solvents for the polymer. A comparison is made between the phase behaviour of polystyrene dissolved in cyclic alkanes and in n-alkanes using free volume polymer solution theory.
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The language of biotechnology: a dictionary of terms j. m. walker and m. cox, acs professional reference book, american chemical society, washington dc, 1988. pp. viii + 255, price £89.91. isbn 0–8412–1489–1 Algal biotechnology edited by t. stadler, j. mollion, m.-c. verdus, y. karamanos, h. morvan and d. christiaen, elsevier science publishers, london, 1989. pp. xii + 522, price £55.00. isbn 1–85166–233–2 Rubber technology handbook werner hofmann, carl hanser verlag, munich, 1989. pp. xv + 611, price dm 86.00. isbn 3–446–14895–7 Developments in the science and technology of composite materials edited by a. r. bunsell, p. lamicq and a. massiah, elsevier science publishers, london, 1989. pp. iii + 835, price £130.00. isbn 1–85166–359–2 International union of pure and applied chemistry—macromolecular chemistry division (iv): commission on macromolecular nomenclature (iv.1)
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