铁电金属-有机骨架[NH4][Zn(HCOO)3]复合材料的相变与铁电性

IF 1.3 4区物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Ferroelectrics Letters Section Pub Date : 2022-05-04 DOI:10.1080/07315171.2022.2076465

H. Nguyen, M. T. Chau, Thi Bich Thao Phan, A. Milinskiy, S. Baryshnikov

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引用次数: 2

摘要

摘要提出了一种利用二氧化硅纳米颗粒(nSiO2)改善典型铁电金属-有机骨架[NH4][Zn(HCOO)3] (AmZn)的相变性能和铁电性的简单方法。结果表明，在nSiO2的影响下，AmZn的一阶过渡类型没有发生改变。随着nSiO2含量从0 wt%增加到40 wt%， AmZn的相变温度显著升高。此外，添加少量nSiO2(< 11%)导致自发饱和度和残余极化率上升。研究还表明，在nSiO2含量高的情况下，很难获得饱和P-E环。

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Phase transition and ferroelectricity of composites based on ferroelectric metal-organic framework of [NH4][Zn(HCOO)3]

Abstract The study suggests a simple approach to improve phase transition properties and ferroelectricity of a typical ferroelectric metal-organic framework of [NH4][Zn(HCOO)3] (AmZn) using silicon dioxides nanoparticles (nSiO2). It is shown that the first-order transition type of AmZn is not changed under the influence of nSiO2. Moreover, the phase transition temperature of AmZn significantly increased with increasing the nSiO2 content from 0 to 40 wt%. Besides, the addition of small nSiO2 content (< 11%) led to rising spontaneous saturation and remnant polarizations. The study also indicated difficulties in obtaining the saturation P-E loops at high nSiO2 content.

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来源期刊

Ferroelectrics Letters Section 物理-物理：凝聚态物理

CiteScore

1.10

自引率

0.00%

发文量

审稿时长

4.8 months

期刊介绍： Ferroelectrics Letters is a separately published section of the international journal Ferroelectrics. Both sections publish theoretical, experimental and applied papers on ferroelectrics and related materials, including ferroelastics, ferroelectric ferromagnetics, electrooptics, piezoelectrics, pyroelectrics, nonlinear dielectrics, polymers and liquid crystals. Ferroelectrics Letters permits the rapid publication of important, quality, short original papers on the theory, synthesis, properties and applications of ferroelectrics and related materials.