Wolfgang A. Herrmann, Richard W. Fischer , João D.G. Correia
{"title":"主族元素和过渡金属之间的多重键。133年一部分。甲基三氧铈作为Baeyer-Villiger氧化反应的催化剂","authors":"Wolfgang A. Herrmann, Richard W. Fischer , João D.G. Correia","doi":"10.1016/S0304-5102(94)87043-8","DOIUrl":null,"url":null,"abstract":"<div><p>Methyltrioxorhenium CH<sub>3</sub>ReO<sub>3</sub> (MTO, <strong>1</strong>) is one of the most active catalysts of the Baeyer-Villiger oxidation of cyclic ketones by use of H<sub>2</sub>O<sub>2</sub> as oxidant. In contrast to the chemistry of established molybdenum and tungsten peroxo complexes, the bis(peroxo) complex [CH<sub>3</sub>ReO(O<sub>2</sub>)<sub>2</sub>·H<sub>2</sub>O] reacts stoichiometrically with ketones. The electronic character of the active species was determined by spectroscopy and by application of an oxygen transfer probe.</p></div>","PeriodicalId":16567,"journal":{"name":"分子催化","volume":"94 2","pages":"Pages 213-223"},"PeriodicalIF":0.0000,"publicationDate":"1994-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0304-5102(94)87043-8","citationCount":"79","resultStr":"{\"title\":\"Multiple bonds between main-group elements and transition metals. Part 133. Methyltrioxorhenium as a catalyst of the Baeyer-Villiger oxidation\",\"authors\":\"Wolfgang A. Herrmann, Richard W. Fischer , João D.G. Correia\",\"doi\":\"10.1016/S0304-5102(94)87043-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Methyltrioxorhenium CH<sub>3</sub>ReO<sub>3</sub> (MTO, <strong>1</strong>) is one of the most active catalysts of the Baeyer-Villiger oxidation of cyclic ketones by use of H<sub>2</sub>O<sub>2</sub> as oxidant. In contrast to the chemistry of established molybdenum and tungsten peroxo complexes, the bis(peroxo) complex [CH<sub>3</sub>ReO(O<sub>2</sub>)<sub>2</sub>·H<sub>2</sub>O] reacts stoichiometrically with ketones. The electronic character of the active species was determined by spectroscopy and by application of an oxygen transfer probe.</p></div>\",\"PeriodicalId\":16567,\"journal\":{\"name\":\"分子催化\",\"volume\":\"94 2\",\"pages\":\"Pages 213-223\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-11-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0304-5102(94)87043-8\",\"citationCount\":\"79\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"分子催化\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0304510294870438\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Chemical Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"分子催化","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304510294870438","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
Multiple bonds between main-group elements and transition metals. Part 133. Methyltrioxorhenium as a catalyst of the Baeyer-Villiger oxidation
Methyltrioxorhenium CH3ReO3 (MTO, 1) is one of the most active catalysts of the Baeyer-Villiger oxidation of cyclic ketones by use of H2O2 as oxidant. In contrast to the chemistry of established molybdenum and tungsten peroxo complexes, the bis(peroxo) complex [CH3ReO(O2)2·H2O] reacts stoichiometrically with ketones. The electronic character of the active species was determined by spectroscopy and by application of an oxygen transfer probe.
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