甘蔗渣基活性炭的合成与表征:氯化锌浸渍率的影响

S. Joshi, Bishnu K.C.
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引用次数: 3

摘要

以蔗渣粉为原料,在ZnCl2与蔗渣粉的浸渍比为0.25:1、0.5:1、1:1和2:1的条件下,采用ZnCl2活化制得系列活性炭。采用碘值、亚甲基蓝值、比表面积、扫描电镜和x射线衍射等方法对活性炭进行了表征。碘值(IN)表明,随着ZnCl2与蔗渣浸渍比的增加,蔗渣的微孔隙率逐渐增加,至1:1后开始降低。介孔率和比表面积逐渐增大。在氯化锌与甘蔗渣浸渍比为1:1的条件下制备的活性炭,碘值达到最大值(868 mg/g)。SEM显微图也显示AC-1表面存在发育良好的孔隙。XRD谱图的宽峰分析表明,活性炭均为非晶材料。实验结果表明,ZnCl2浸渍对蔗渣活性炭的孔隙率和比表面积的发展是有效的。
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Synthesis and Characterization of Sugarcane Bagasse Based Activated Carbon: Effect of Impregnation Ratio of ZnCl2
Series of activated carbons (ACs) have been prepared from sugarcane bagasse powder by ZnCl2 activation at various impregnation ratios of ZnCl2 to Sugarcane bagasse powder of 0.25:1, 0.5:1, 1:1 and 2:1 by weight. Characteristics of the activated carbons (ACs) were determined by iodine number, methylene blue number, surface area, scanning electron microscopy (SEM) and x-ray diffraction. Iodine number (IN) indicated that, microporosity of the AC were increased with increasing impregnation ratio ZnCl2 to Sugarcane bagasse upto 1:1 then started to decrease. However, mesoporosity as well as surface area was increased progressively. The maximum value of iodine number (868 mg/g) was achieved in the AC prepared at impregnation ratio of ZnCl2 to Sugarcane bagasse of 1:1. SEM micrographs also show the presence of well developed pores on its surface of AC-1. The broad peaks in the XRD patterns indicated that, all the ACs is amorphous materials. From results, it is concluded that ZnCl2 concentration used in impregnation is effective for development of porosity and surface area of the AC prepared from sugarcane bagasse.
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