Cost-Effective Chemical EOR for Heterogenous Carbonate Reservoirs Using a Ketone-Surfactant System

The complexity, high cost, and potential environmental concerns of chemical enhanced oil recovery (EOR) methods have diminished their field applications considerably. However, considering the significant incremental oil recoveries that can be obtained from these methods encourage researchers to explore ways to reduce both complexity, cost, and environmental concerns of such systems. This is especially important in carbonate formations, where after waterflooding, much of the oil remains trapped in complex reservoir pores—especially if the reservoir contains an interconnected fracture network of flow channels within the bulk rock matrix. In this paper, we present an experimental assessment of several simple chemical EOR waterflooding systems comprising of small concentrations of a low cost, low molecular weight ketone and a non-ionic surfactant in association with low-salinity brine. The experiments were conducted in carbonate cores from a Permian Basin San Andres Formation. Four different oil displacement scenarios were investigated using San Andres carbonate cores from the Central Vacuum Field in New Mexico. This included 1) low-salinity brine, 2) low-salinity brine with a surfactant, 3) low-salinity brine with a ketone, and 4) low-salinity brine with a combined ketone-surfactant system. Static imbibition experiments were conducted using a spontaneous imbibition apparatus in addition to the use of a high-speed centrifuge to saturate the cores to irreducible brine saturation. Adding a 1% concentration of 3-pentanone and a 1% non-ionic surfactant to a low-salinity brine yielded oil recoveries of 44% from the 3-pentanone system, compared to 11.4% from low-salinity brine only. The oil recovery is enhanced by a single mechanism or synergy of several mechanisms that includes interfacial tension (IFT) reduction by surfactant, capillary imbibition, favorable wettability alteration by ketone, and osmotic low-salinity brine imbibition. The IFT decreased to 1.79 mN/m upon addition of non-ionic surfactant to low-salinity brine, and it reduced to 2.96 mN/m in a mixture of 3-pentanone and non-ionic surfactant in low-salinity brine. Furthermore, ketone improved the core wettability by reducing the contact angle to 43.9° from 50.7° in the low-salinity brine experiment. In addition, the low-salinity brine systems caused mineral dissolution, which created an alkali environment confirmed by an increase in the brine pH. We believe the increase in pH increased the hydrophilic character of the pores; thus, increasing oil recovery.